Biotransformation and pharmacokinetics of the novel anticancer drug, SYUIQ-5, in the rat

Invest New Drugs. 2008 Apr;26(2):119-37. doi: 10.1007/s10637-007-9089-9. Epub 2007 Oct 6.

Abstract

SYUIQ-5, a novel telomerase inhibitor, has demonstrated antitumor activity in nude mouse studies. The objective of the present study was to examine the metabolism and pharmacokinetics of SYUIQ-5 in rats. The plasma pharmacokinetics of SYUIQ-5 was nonlinear following i.p. administration at 15, 30 and 60 mg/kg. SYUIQ-5 metabolism in rat liver microsomes followed Michaelis-Menten kinetics, with Km and Vmax values of 12.3 microM and 2.01 nmol/min/mg protein, respectively. Ketoconazole significantly inhibited the metabolism of SYUIQ-5 in liver microsomes from rats pretreated with control vehicle or various inducers, whereas sulphaphenazole, ticlopidine, quinidine, and methylpyrazole had no inhibitory effects on SYUIQ-5 metabolism. Dexamethasone and beta-naphthoflavone (BNF), but not phenobarbital and ethanol, significantly induced SYUIQ-5 metabolism in rats. Alpha-naphthoflavone significantly inhibited SYUIQ-5 metabolism in liver microsomes from BNF-pretreated rats. Similar to other secondary amines, SYUIQ-5 underwent N-demethylation and O-oxygenation to at least two metabolites by rat liver microsomes. Pretreatment of rats with SYUIQ-5 at 0.1, 5 or 10 mg/kg for 5 days significantly induced the expression and activity of rat Cyp1A1/2, and induced Cyp3A1/2 expression at 10 mg/kg, but not Cyp2E1 and 2B1/2. These results indicate that that SYUIQ-5 exhibits dose-dependent pharmacokinetics in rats and it is mainly metabolized by Cyp3A1/2.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Antineoplastic Agents / administration & dosage
  • Antineoplastic Agents / pharmacokinetics*
  • Aryl Hydrocarbon Hydroxylases / metabolism*
  • Cytochrome P-450 CYP1A1 / metabolism
  • Cytochrome P-450 CYP1A2 / metabolism
  • Cytochrome P-450 CYP3A
  • Diamines / administration & dosage
  • Diamines / pharmacokinetics*
  • Dose-Response Relationship, Drug
  • Drug Evaluation, Preclinical
  • Injections, Intraperitoneal
  • Male
  • Membrane Proteins / metabolism*
  • Microsomes, Liver / metabolism
  • Quinolines / administration & dosage
  • Quinolines / pharmacokinetics*
  • Random Allocation
  • Rats
  • Rats, Sprague-Dawley
  • Telomerase / antagonists & inhibitors

Substances

  • Antineoplastic Agents
  • Diamines
  • Membrane Proteins
  • N'-(10H-indolo(3,2-b)quinolin-11-yl)-N,N-dimethylpropane-1,3-diamine
  • Quinolines
  • Aryl Hydrocarbon Hydroxylases
  • Cyp3a2 protein, rat
  • Cyp3a23-3a1 protein, rat
  • Cytochrome P-450 CYP1A1
  • Cytochrome P-450 CYP1A2
  • Cytochrome P-450 CYP3A
  • Telomerase