Mechanism of inhibition of DNA gyrase by ES-1273, a novel DNA gyrase inhibitor

Microbiol Immunol. 2007;51(10):977-84. doi: 10.1111/j.1348-0421.2007.tb03994.x.

Abstract

We investigated the mode of action of ES-1273, a novel DNA gyrase inhibitor obtained by optimization of ES-0615, which was found by screening our chemical library using anucleate cell blue assay. ES-1273 exhibited the same antibacterial activity against S. aureus strains with amino acid change(s) conferring quinolone- and coumarin-resistance as that against a susceptible strain. In addition, ES-1273 inhibited DNA gyrase supercoiling activity, but not ATPase activity of the GyrB subunit of DNA gyrase. Moreover, ES-1273 did not induce cleavable complex. These findings demonstrate that the mechanism by which ES-1273 inhibits DNA gyrase is different from that of the quinolones or the coumarins. Preincubation of DNA gyrase and substrate DNA prevented inhibition of DNA gyrase supercoiling activity by ES-1273. ES-1273 antagonized quinolone-induced cleavage. In electrophoretic mobility shift assay, no band representing DNA gyrase-DNA complex was observed in the presence of ES-1273. Taken together, these results indicate that ES-1273 prevents DNA from binding to DNA gyrase. Furthermore, our results from surface plasmon resonance experiments strongly suggest that ES-1273 interacts with DNA. Therefore, the interaction between ES-1273 and DNA prevents DNA from binding to DNA gyrase, resulting in inhibition of DNA gyrase supercoiling. Interestingly, we also found that ES-1273 inhibits topoisomerase IV and human topoisomerase IIalpha, but not human topoisomerase I. These findings indicate that ES-1273 is a type II topoisomerase specific inhibitor.

MeSH terms

  • Anti-Bacterial Agents / pharmacology*
  • DNA, Bacterial / metabolism
  • DNA, Superhelical / antagonists & inhibitors
  • DNA, Superhelical / metabolism
  • Drug Resistance, Bacterial
  • Enzyme Inhibitors / chemistry
  • Enzyme Inhibitors / pharmacology*
  • Escherichia coli / drug effects*
  • Escherichia coli / enzymology
  • Gram-Positive Cocci / drug effects*
  • Gram-Positive Cocci / enzymology
  • Microbial Sensitivity Tests
  • Pyrazoles / chemistry*
  • Pyrazoles / pharmacology*
  • Staphylococcus aureus / drug effects*
  • Staphylococcus aureus / enzymology
  • Topoisomerase II Inhibitors*

Substances

  • Anti-Bacterial Agents
  • DNA, Bacterial
  • DNA, Superhelical
  • Enzyme Inhibitors
  • Pyrazoles
  • Topoisomerase II Inhibitors