Formation of a 3D porous ferric arsenate containing novel cubane-like Fe4F4 building units

Zhihui Yi; Chao Yang; Wujiong Xia; Xianzhu Xu; Xiao Zhang

doi:10.1021/ic900892q

Formation of a 3D porous ferric arsenate containing novel cubane-like Fe4F4 building units

Inorg Chem. 2009 Nov 2;48(21):9959-61. doi: 10.1021/ic900892q.

Authors

Zhihui Yi¹, Chao Yang, Wujiong Xia, Xianzhu Xu, Xiao Zhang

Affiliation

¹ State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.

PMID: 19785467
DOI: 10.1021/ic900892q

Abstract

The purely inorganic microporous compound [H(3)O][Fe(4)F(4)(AsO(4))(3)] x 3 H(2)O (1), which contains novel cubane-like Fe(4)F(4) cages, exhibiting a 3D configuration with channels of dimensions 8 A x 8 A running along the [001], [010], and [100] directions, presents antiferromagnetic interactions.