Measuring ensemble-averaged surface-enhanced Raman scattering in the hotspots of colloidal nanoparticle dimers and trimers

J Am Chem Soc. 2010 Mar 24;132(11):3644-5. doi: 10.1021/ja9090885.

Abstract

We report ensemble-averaged measurements of colloidal hotspots enabled by the synthesis of highly uniform dimers and trimers of Au@Ag nanoparticles and the quantification of the relative concentrations of the nanoclusters.