Cytotoxic clerodane diterpenes from Casearia rupestris

J Nat Prod. 2011 Apr 25;74(4):776-81. doi: 10.1021/np100840w. Epub 2011 Mar 7.

Abstract

Four new clerodane diterpenes, casearupestrins A-D (1-4), were isolated from the leaves of Casearia rupestris. Compounds 1 and 4 were acetylated to yield 2,7-di-O-acetylcasearupestrin A (5) and 2,6-di-O-acetylcasearupestrin D (6). All compounds were evaluated for cytotoxicity against a small panel of human cancer cell lines. Casearupestrin A (1) exhibited the most potent activity against MDA/MB-435 (human melanoma) and SF-295 (human glioblastoma) cells, superior to that of the standard drug doxorubicin.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Antineoplastic Agents, Phytogenic / chemistry
  • Antineoplastic Agents, Phytogenic / isolation & purification*
  • Antineoplastic Agents, Phytogenic / pharmacology*
  • Brasilien
  • Casearia / chemistry*
  • Diterpenes, Clerodane / chemistry
  • Diterpenes, Clerodane / isolation & purification*
  • Diterpenes, Clerodane / pharmacology*
  • Doxorubicin / pharmacology
  • Drug Screening Assays, Antitumor
  • Humans
  • Molecular Structure
  • Plant Leaves / chemistry

Substances

  • Antineoplastic Agents, Phytogenic
  • Diterpenes, Clerodane
  • Doxorubicin