Porous zirconia/hydroxyapatite scaffolds for bone reconstruction

Dent Mater. 2012 Dec;28(12):1221-31. doi: 10.1016/j.dental.2012.09.001. Epub 2012 Sep 25.

Abstract

Objective: Highly porous apatite-based bioceramic scaffolds have been widely investigated as three-dimensional (3D) templates for cell adhesion, proliferation, and differentiation promoting the bone regeneration. Their fragility, however, limits their clinical application especially for a large bone defect.

Methods: To address the hypothesis that using a ZrO(2)/hydroxyapatite (HAp) composite might improve both the mechanical properties and cellular compatibility of the porous material, we fabricated ZrO(2)/HAp composite scaffolds with different ZrO(2)/HAp ratios, and evaluated their characteristics. In addition, porous ZrO(2)/HAp scaffolds containing bone marrow derived stromal cells (BMSCs) were implanted into critical-size bone defects for 6 weeks in order to evaluate the bone tissue reconstruction with this material.

Results: The porosity of a ZrO(2)/HAp scaffold can be adjusted from 72% to 91%, and the compressive strength of the scaffold increased from 2.5 to 13.8MPa when the ZrO(2) content increased from 50 to 100wt%. The cell adhesion and proliferation in the ZrO(2)/HAp scaffold was greatly improved when compared to the scaffold made with ZrO(2) alone. Moreover, in vivo study showed that a BMSCs-loaded ZrO(2)/HAp scaffold provided a suitable 3D environment for BMSC survival and enhanced bone regeneration around the implanted material.

Significance: We thus showed that a porous ZrO(2)/HAp composite scaffold has excellent mechanical properties, and cellular/tissue compatibility, and would be a promising substrate to achieve both bone reconstruction and regeneration needed in the treatment of large bone defects.

Publication types

  • Comparative Study

MeSH terms

  • 3T3 Cells
  • Animals
  • Biocompatible Materials / chemical synthesis
  • Biocompatible Materials / chemistry*
  • Biomechanical Phenomena
  • Bone Diseases / surgery*
  • Bone Marrow Cells / physiology
  • Bone Regeneration / physiology
  • Cell Adhesion / physiology
  • Cell Proliferation
  • Cell Survival / physiology
  • Collagen Type I / analysis
  • Compressive Strength
  • Crystallography, X-Ray
  • Durapatite / chemical synthesis
  • Durapatite / chemistry*
  • Male
  • Mice
  • Microscopy, Electron, Scanning
  • Microscopy, Electron, Transmission
  • Osteoblasts / physiology
  • Osteogenesis / physiology
  • Osteopontin / analysis
  • Parietal Bone / surgery
  • Plastic Surgery Procedures / methods*
  • Porosity
  • Rats
  • Stromal Cells / physiology
  • Tissue Engineering / methods
  • Tissue Scaffolds / chemistry*
  • Zirconium / chemistry*

Substances

  • Biocompatible Materials
  • Collagen Type I
  • Spp1 protein, rat
  • Osteopontin
  • Durapatite
  • Zirconium
  • zirconium oxide