Abstract
2-Arylphenols were conveniently synthesized from aryl iodides and 6-diazo-2-cyclohexenones, in moderate to excellent yields, via tandem Pd-catalyzed cross-coupling/aromatization. The preliminary results for the corresponding enantioselective version showed that the coupling products could be generated in up to 72% ee.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Azo Compounds / chemistry*
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Catalysis
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Combinatorial Chemistry Techniques
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Cyclohexanones / chemistry*
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Hydrocarbons, Iodinated / chemistry*
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Molecular Structure
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Palladium / chemistry*
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Phenols / chemical synthesis*
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Phenols / chemistry
Substances
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Azo Compounds
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Cyclohexanones
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Hydrocarbons, Iodinated
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Phenols
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Palladium