Assessment of radioligands for PET imaging of cyclooxygenase-2 in an ischemic neuronal injury model

Brain Res. 2013 Oct 2:1533:152-62. doi: 10.1016/j.brainres.2013.08.026. Epub 2013 Aug 20.

Abstract

Cyclooxygenase-2 (COX-2) plays crucial roles in progressive neuronal death in ischemic brain injury. In the present study, we evaluated two radiolabeled COX-2 selective inhibitors, [11C]celecoxib and [11C]rofecoxib, as positron emission tomography (PET) tracers for COX-2 imaging in normal and ischemic mouse brains. We also took advantage of our newly-generated antibody highly selective for mouse COX-2 to prove accumulation of the radioligands in regions enriched with COX-2. In vitro autoradiography demonstrated specific binding of high-concentration [11C]rofecoxib but not [11C]celecoxib to the cerebellum and brain stem of normal brains wherein COX-2 immunoreactivity in neurons was most abundantly observed. Meanwhile, both of these radioligands failed to detect COX-2 expression in PET assays despite their excellent brain permeability. Hypoperfusion-induced ischemia caused marked necrotic neuron death accompanied by gliosis and enhancement of neuronal COX-2 immunoreactivity in the hippocampus. Correspondingly, in vitro autoradiographic binding of [11C]rofecoxib was increased in the injured hippocampus compared to the uninjured contralateral region, but failed in living brains of ischemia model likewise. Our work provides the rationale for monitoring COX-2 as a biomarker reflecting ischemic brain injuries and demonstrates that [11C]rofecoxib, not [11C]celecoxib, is useful for in vitro assays of COX-2, but its affinity would be insufficient for in vivo PET visualization.

Keywords: Autoradiography; Brain ischemia; Cyclooxygenase-2 (COX-2); Inflammation; Molecular imaging; Positron emission tomography (PET).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Antibodies
  • Brain / diagnostic imaging*
  • Brain / enzymology
  • Brain Ischemia / diagnostic imaging*
  • Brain Ischemia / enzymology
  • Carbon Radioisotopes
  • Celecoxib
  • Cyclooxygenase 2 / immunology
  • Cyclooxygenase 2 / metabolism*
  • Disease Models, Animal
  • Lactones / administration & dosage*
  • Male
  • Mice
  • Mice, Inbred C57BL
  • Positron-Emission Tomography / methods
  • Pyrazoles / administration & dosage*
  • Sulfonamides / administration & dosage*
  • Sulfones / administration & dosage*

Substances

  • Antibodies
  • Carbon Radioisotopes
  • Lactones
  • Pyrazoles
  • Sulfonamides
  • Sulfones
  • rofecoxib
  • Ptgs2 protein, mouse
  • Cyclooxygenase 2
  • Celecoxib