Effect of protein binding on unbound atazanavir and darunavir cerebrospinal fluid concentrations

J Clin Pharmacol. 2014 Sep;54(9):1063-71. doi: 10.1002/jcph.298. Epub 2014 Apr 8.

Abstract

HIV-1 protease inhibitors (PIs) exhibit different protein binding affinities and achieve variable plasma and tissue concentrations. Degree of plasma protein binding may impact central nervous system penetration. This cross-sectional study assessed cerebrospinal fluid (CSF) unbound PI concentrations, HIV-1 RNA, and neopterin levels in subjects receiving either ritonavir-boosted darunavir (DRV), 95% plasma protein bound, or atazanavir (ATV), 86% bound. Unbound PI trough concentrations were measured using rapid equilibrium dialysis and liquid chromatography/tandem mass spectrometry. Plasma and CSF HIV-1 RNA and neopterin were measured by Ampliprep/COBAS® Taqman® 2.0 assay (Roche) and enzyme-linked immunosorbent assay (ALPCO), respectively. CSF/plasma unbound drug concentration ratio was higher for ATV, 0.09 [95% confidence interval (CI) 0.06-0.12] than DRV, 0.04 (95%CI 0.03-0.06). Unbound CSF concentrations were lower than protein adjusted wild-type inhibitory concentration-50 (IC50 ) in all ATV and 1 DRV-treated subjects (P < 0.001). CSF HIV-1 RNA was detected in 2/15 ATV and 4/15 DRV subjects (P = 0.65). CSF neopterin levels were low and similar between arms. ATV relative to DRV had higher CSF/plasma unbound drug ratio. Low CSF HIV-1 RNA and neopterin suggest that both regimens resulted in CSF virologic suppression and controlled inflammation.

Keywords: HIV/AIDS; central nervous system; clinical pharmacology.

Publication types

  • Clinical Trial
  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adult
  • Anti-HIV Agents / administration & dosage
  • Anti-HIV Agents / blood
  • Anti-HIV Agents / cerebrospinal fluid
  • Anti-HIV Agents / pharmacokinetics*
  • Atazanavir Sulfate
  • Blood Proteins / metabolism
  • Darunavir
  • Drug Therapy, Combination
  • Female
  • HIV Infections / blood
  • HIV Infections / cerebrospinal fluid
  • HIV Infections / metabolism
  • HIV Infections / virology
  • HIV-1 / genetics
  • Humans
  • Male
  • Middle Aged
  • Neopterin / blood
  • Neopterin / cerebrospinal fluid
  • Oligopeptides / administration & dosage
  • Oligopeptides / blood
  • Oligopeptides / cerebrospinal fluid
  • Oligopeptides / pharmacokinetics*
  • Protein Binding
  • Pyridines / administration & dosage
  • Pyridines / blood
  • Pyridines / cerebrospinal fluid
  • Pyridines / pharmacokinetics*
  • RNA, Viral / blood
  • RNA, Viral / cerebrospinal fluid
  • Ritonavir / administration & dosage
  • Sulfonamides / administration & dosage
  • Sulfonamides / blood
  • Sulfonamides / cerebrospinal fluid
  • Sulfonamides / pharmacokinetics*

Substances

  • Anti-HIV Agents
  • Blood Proteins
  • Oligopeptides
  • Pyridines
  • RNA, Viral
  • Sulfonamides
  • Atazanavir Sulfate
  • Neopterin
  • Ritonavir
  • Darunavir