Carbon quantum dot/NiFe layered double-hydroxide composite as a highly efficient electrocatalyst for water oxidation

ACS Appl Mater Interfaces. 2014 May 28;6(10):7918-25. doi: 10.1021/am501256x. Epub 2014 Apr 25.

Abstract

The design of highly efficient, durable, and earth-abundant catalysts for the oxygen evolution reaction is crucial to a variety of important energy conversion and storage processes. Here, we use carbon quantum dots (CQDs, ∼5 nm) to form hybrids with the ultrathin nickel-iron layered double-hydroxide (NiFe-LDH) nanoplates. The resulting CQD/NiFe-LDH complex exhibits high electrocatalytic activity (with an overpotential of ∼235 mV in 1 M KOH at a current density of 10 mA cm(-2)) and stability for oxygen evolution, which almost exceed the values of all previously reported Ni-Fe compounds and were comparable to those of the most active perovskite-based catalyst.

Publication types

  • Research Support, Non-U.S. Gov't