Small-molecule inhibitors of JC polyomavirus infection

J Pept Sci. 2015 Mar;21(3):236-42. doi: 10.1002/psc.2731. Epub 2014 Dec 19.

Abstract

The JC polyomavirus (JCPyV) infects approximately 50% of the human population. In healthy individuals, the infection remains dormant and asymptomatic, but in immuno-suppressed patients, it can cause progressive multifocal leukoencephalopathy (PML), a potentially fatal demyelinating disease. Currently, there are no drugs against JCPyV infection nor for the treatment of PML. Here, we report the development of small-molecule inhibitors of JCPyV that target the initial interaction between the virus and host cell and thereby block viral entry. Utilizing a combination of computational and NMR-based screening techniques, we target the LSTc tetrasaccharide binding site within the VP1 pentameric coat protein of JCPyV. Four of the compounds from the screen effectively block viral infection in our in vitro assays using SVG-A cells. For the most potent compound, we used saturation transfer difference NMR to determine the mode of binding to purified pentamers of JCPyV VP1. Collectively, these results demonstrate the viability of this class of compounds for eventual development of JCPyV-antiviral therapeutics.

Keywords: polyomavirus; progressive multifocal leukoencephalopathy; saturation transfer difference NMR; small molecular screening.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Animals
  • Antiviral Agents / chemical synthesis
  • Antiviral Agents / chemistry*
  • Binding Sites
  • Biological Assay
  • COS Cells
  • Capsid Proteins / antagonists & inhibitors*
  • Capsid Proteins / chemistry
  • Capsid Proteins / genetics
  • Cell Line, Transformed
  • Chlorocebus aethiops
  • Escherichia coli / genetics
  • Escherichia coli / metabolism
  • Gene Expression
  • HEK293 Cells
  • Humans
  • JC Virus / drug effects*
  • JC Virus / growth & development
  • JC Virus / metabolism
  • Molecular Docking Simulation
  • Neuroglia / drug effects
  • Neuroglia / virology
  • Protein Binding / drug effects
  • Protein Multimerization
  • Recombinant Proteins / chemistry
  • Recombinant Proteins / genetics
  • Small Molecule Libraries / chemical synthesis
  • Small Molecule Libraries / chemistry
  • Small Molecule Libraries / pharmacology*
  • Virus Internalization / drug effects*

Substances

  • Antiviral Agents
  • Capsid Proteins
  • Recombinant Proteins
  • Small Molecule Libraries
  • VP1 protein, polyomavirus