A Simple and Improved Active Loading Method to Efficiently Encapsulate Staurosporine into Lipid-Based Nanoparticles for Enhanced Therapy of Multidrug Resistant Cancer

Pharm Res. 2016 May;33(5):1104-14. doi: 10.1007/s11095-015-1854-4. Epub 2016 Jan 12.

Abstract

Purpose: This study was aimed at developing a new active loading method to stably encapsulate staurosporine (STS), a water insoluble drug, into lipid-based nanoparticles (LNPs) for drug targeting to tumors.

Methods: A limited amount of DMSO was included during the active loading process to prevent precipitation and facilitate the loading of insoluble STS into the aqueous core of a LNP. The drug loading kinetics under various conditions was studied and the STS-LNPs were characterized by size, drug-to-lipid ratio, drug release kinetics and in vitro potency. The antitumor efficacy of the STS-LNPs was compared with free STS in a mouse model.

Results: The drug loading efficiency reached 100% within 15 min of incubation at a drug-to-lipid ratio of 0.31 (mol) via an ammonium gradient. STS formed nano-aggregates inside the aqueous core of the LNPs and was stably retained upon storage and in the presence of serum. A 3-fold higher dose of the STS-LNPs could be tolerated by BALB/c mice compared with free STS, leading to nearly complete growth inhibition of a multidrug resistant breast tumor, while free STS only exhibited moderate activity.

Conclusion: This simple and efficient drug loading method produced a stable LNP formulation for STS that was effective for cancer treatment.

Keywords: Active loading; Liposome; Multidrug resistant cancer; Staurosporine; Water insoluble drug.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Cell Line, Tumor
  • Dimethyl Sulfoxide / chemistry
  • Drug Delivery Systems
  • Drug Resistance, Multiple
  • Drug Resistance, Neoplasm
  • Female
  • Humans
  • Lipids / chemistry*
  • Liposomes / chemistry*
  • Liposomes / ultrastructure
  • Mice, Inbred BALB C
  • Models, Molecular
  • Nanoparticles / chemistry*
  • Nanoparticles / ultrastructure
  • Neoplasms / drug therapy*
  • Neoplasms / pathology
  • Particle Size
  • Protein Kinase Inhibitors / administration & dosage*
  • Protein Kinase Inhibitors / therapeutic use
  • Staurosporine / administration & dosage*
  • Staurosporine / therapeutic use

Substances

  • Lipids
  • Liposomes
  • Protein Kinase Inhibitors
  • Staurosporine
  • Dimethyl Sulfoxide