Covalent immobilization of glycosaminoglycans to reduce the inflammatory effects of biomaterials

Int J Artif Organs. 2016 Jan;39(1):37-44. doi: 10.5301/ijao.5000468. Epub 2016 Feb 23.

Abstract

Background: The inflammatory responses evoked by artificial organs and implantation of devices like biosensors and guide wires can lead to acute and chronic inflammation, largely limiting the functionality and longevity of the devices with negative effects on patients.

Aims: The present study aimed to reduce the inflammatory responses to biomaterials by covalent immobilization of glycosaminoglycans (GAGs) on amino-terminated surfaces used as model biomaterials here.

Methods and results: Water contact angle (WCA) and zeta potential measurements showed a significant increase in wettability and negative charges on the GAG-modified surfaces, respectively, confirming the successful immobilization of GAGs on the amino-terminated surfaces. THP-1-derived macrophages were used as a model cell type to investigate the efficacy of GAG-modified surfaces in modulating inflammatory responses. It was found that macrophage adhesion, macrophage spreading morphology, foreign body giant cell (FBGC) formation, as well as β1 integrin expression and interleukin-1β (IL-1β) production were all significantly decreased on GAG-modified surfaces compared to the initial amino-terminated surface.

Conclusions: This study demonstrates the potential of covalent GAG immobilization to reduce the inflammatory potential of biomaterials in different clinical settings.

MeSH terms

  • Artificial Organs / adverse effects
  • Biocompatible Materials / adverse effects*
  • Cells, Cultured
  • Equipment and Supplies / adverse effects
  • Glycosaminoglycans / pharmacology*
  • Humans
  • Inflammation / etiology
  • Inflammation / prevention & control*
  • Macrophages / drug effects
  • Macrophages / metabolism
  • Materials Testing
  • Prostheses and Implants / adverse effects*
  • Surface Properties*
  • Th1 Cells / drug effects
  • Th1 Cells / metabolism

Substances

  • Biocompatible Materials
  • Glycosaminoglycans