Key interactions by conserved polar amino acids located at the transmembrane helical boundaries in Class B GPCRs modulate activation, effector specificity and biased signalling in the glucagon-like peptide-1 receptor

Biochem Pharmacol. 2016 Oct 15:118:68-87. doi: 10.1016/j.bcp.2016.08.015. Epub 2016 Aug 26.

Abstract

Class B GPCRs can activate multiple signalling effectors with the potential to exhibit biased agonism in response to ligand stimulation. Previously, we highlighted key TM domain polar amino acids that were crucial for the function of the GLP-1 receptor, a key therapeutic target for diabetes and obesity. Using a combination of mutagenesis, pharmacological characterisation, mathematical and computational molecular modelling, this study identifies additional highly conserved polar residues located towards the TM helical boundaries of Class B GPCRs that are important for GLP-1 receptor stability and/or controlling signalling specificity and biased agonism. This includes (i) three positively charged residues (R3.30227, K4.64288, R5.40310) located at the extracellular boundaries of TMs 3, 4 and 5 that are predicted in molecular models to stabilise extracellular loop 2, a crucial domain for ligand affinity and receptor activation; (ii) a predicted hydrogen bond network between residues located in TMs 2 (R2.46176), 6 (R6.37348) and 7 (N7.61406 and E7.63408) at the cytoplasmic face of the receptor that is important for stabilising the inactive receptor and directing signalling specificity, (iii) residues at the bottom of TM 5 (R5.56326) and TM6 (K6.35346 and K6.40351) that are crucial for receptor activation and downstream signalling; (iv) residues predicted to be involved in stabilisation of TM4 (N2.52182 and Y3.52250) that also influence cell signalling. Collectively, this work expands our understanding of peptide-mediated signalling by the GLP-1 receptor.

Keywords: Biased agonism; Cell signaling; G protein-coupled receptor; Glucagon-like peptide-1 receptor.

MeSH terms

  • Amino Acid Motifs
  • Amino Acid Substitution
  • Animals
  • Binding Sites
  • CHO Cells
  • Conserved Sequence
  • Cricetulus
  • Glucagon-Like Peptide-1 Receptor / agonists
  • Glucagon-Like Peptide-1 Receptor / chemistry
  • Glucagon-Like Peptide-1 Receptor / genetics
  • Glucagon-Like Peptide-1 Receptor / metabolism*
  • Humans
  • Hydrogen Bonding
  • Kinetics
  • Ligands
  • Models, Molecular*
  • Molecular Docking Simulation
  • Mutagenesis, Site-Directed
  • Mutant Proteins / chemistry
  • Mutant Proteins / metabolism*
  • Protein Interaction Domains and Motifs
  • Protein Stability
  • Radioligand Assay
  • Recombinant Proteins / chemistry
  • Recombinant Proteins / metabolism
  • Signal Transduction*
  • Structural Homology, Protein

Substances

  • GLP1R protein, human
  • Glucagon-Like Peptide-1 Receptor
  • Ligands
  • Mutant Proteins
  • Recombinant Proteins