Complexes of myo-Inositol-Hexakisphosphate (IP6) with Zinc or Lanthanum for the Decorporation of Radiocesium

Chem Pharm Bull (Tokyo). 2017;65(3):261-267. doi: 10.1248/cpb.c16-00792.

Abstract

Radioactive nuclides leak into the surrounding environment after nuclear power plant disasters, such as the Chernobyl accident and the Fukushima Daiichi Nuclear Power Plant disaster. Cesium-137 (137Cs) (t1/2=30.1 year), a water-soluble radionuclide with a long physical half-life, contaminates aquatic ecosystems and food products. In humans, 137Cs concentrates in muscle tissue and has a long biological half-life, indicating it may be harmful. myo-Inositol-hexakisphosphate (IP6) is a compound found in grain, beans, and oil seeds. IP6 has the ability to form insoluble complexes with metals, including lanthanum (La) and zinc (Zn). We hypothesized that La-IP6 and Zn-IP6 may promote the elimination of 137Cs from the body through the adsorption of La-IP6 and Zn-IP6 to 137Cs in the gastrointestinal tract. Therefore, in this study, we evaluated the adsorptive capacity of La-IP6 and Zn-IP6 complexes with 137Cs in vitro and in vivo. La-IP6 and Zn-IP6 complexes were stable in acidic solution (pH 1.2) at 37°C. In vitro binding assays indicated that La-IP6 and Zn-IP6 complexes adsorbed 137Cs, with the adsorption capacity of Zn-IP6 to 137Cs greater than that of La-IP6. To evaluate the usefulness of La-IP6 and Zn-IP6 in vivo, La-IP6 or Zn-IP6 was administrated to mice after intravenous injection of 137Cs. However, the biodistribution of 137Cs in the La-IP6 treated group and the Zn-IP6 treated group was nearly identical to the non-treated control group, indicating that La-IP6 and Zn-IP6 were not effective at promoting the elimination of 137Cs in vivo.

MeSH terms

  • Administration, Oral
  • Adsorption
  • Animals
  • Calcium / chemistry
  • Cesium Radioisotopes / administration & dosage
  • Cesium Radioisotopes / chemistry
  • Cesium Radioisotopes / pharmacokinetics*
  • Lanthanum / administration & dosage
  • Lanthanum / chemistry
  • Lanthanum / pharmacokinetics*
  • Male
  • Mice
  • Mice, Inbred Strains
  • Phytic Acid / administration & dosage
  • Phytic Acid / chemistry
  • Phytic Acid / pharmacokinetics*
  • Potassium / chemistry
  • Sodium / chemistry
  • Tissue Distribution
  • Zinc / administration & dosage
  • Zinc / chemistry
  • Zinc / pharmacokinetics*

Substances

  • Cesium Radioisotopes
  • Lanthanum
  • Phytic Acid
  • Sodium
  • Zinc
  • Potassium
  • Calcium