Structural elucidation and antioxidant activity of an arabinogalactan from the leaves of Moringa oleifera

Int J Biol Macromol. 2018 Jun:112:126-133. doi: 10.1016/j.ijbiomac.2018.01.110. Epub 2018 Jan 31.

Abstract

A novel arabinogalactan (MOP-1) was isolated from leaves of Moringa oleifera and was purified by macro-porous resin, DEAE-52 Cellulose and Sepharose 6B gel filtration chromatography. High performance gel permeation chromatography (HPGPC) analysis showed that the molecular weight of MOP-1 was 7.65 × 107 Da. Monosaccharide composition analysis indicated that sugar composition is Rha: Ara: Gal in a molar ratio of 1:7.32:12.12. Structural analysis indicated that MOP-1 has a backbone of →1)-β-d-Galp-(3,4→ with highly branched chains at O-4 position. The branches were composed of →1)-β-d-Galp-(4→, →1)-α-d-Galp-(2→, Araf-(1→, Galp-(1→. Its antioxidant activities were evaluated by DPPH radical scavenging capacity, 2,2'-Azinobis-(3-ethylbenzthiazoline-6-sulphonate) (ABTS) radical cation scavenging capacity, and ferric-reducing antioxidant power (FRAP). The results indicated MOP-1 exhibited significant antioxidant activities.

Keywords: Antioxidant activity; Arabinogalactan; Moringa oleifera; Structural characterization.

MeSH terms

  • Antioxidants / chemistry*
  • Antioxidants / isolation & purification
  • Benzothiazoles / chemistry
  • Free Radical Scavengers / chemistry*
  • Free Radical Scavengers / isolation & purification
  • Galactans / chemistry*
  • Galactans / isolation & purification
  • Molecular Weight
  • Monosaccharides / chemistry
  • Monosaccharides / isolation & purification
  • Moringa oleifera / chemistry*
  • Plant Leaves / chemistry
  • Polysaccharides / chemistry
  • Polysaccharides / isolation & purification
  • Sulfonic Acids / chemistry

Substances

  • Antioxidants
  • Benzothiazoles
  • Free Radical Scavengers
  • Galactans
  • Monosaccharides
  • Polysaccharides
  • Sulfonic Acids
  • 2,2'-azino-di-(3-ethylbenzothiazoline)-6-sulfonic acid
  • arabinogalactan