Delineating the origin of Pb and Cd in the urban dust through elemental and stable isotopic ratio: A study from Hangzhou City, China

Urban dust (UD) is one of the main sinks of heavy metals in urban environments; however, the sources of these heavy metals are quite difficult to identify. A total of 78 UD samples were collected bi-monthly from October 2012 to August 2013, including 13 sites from three functional areas (residential areas, city parks, and main roads) and the Botanic Garden as a control district. The metal ratios and lead isotopic ratios combined with correlation analysis were used to identify the sources of Pb and Cd in the UD samples. In the scatter plot of Cd/Mn vs Pb/Mn, the dust samples could be classified into four groups showing their different sources and characteristics. Lead isotopic composition analysis indicated that coal combustion was the main source of Pb for residential dusts, while automobile exhaust emission for road dusts. Correlation analysis revealed that the abraded paints was a main contribution of Cd in UD, especially those in city parks. The research provides a useful method of combining multiple approaches to identify sources of metal elements in UD.