CuMo_xW_(1-x)O₄ Solid Solution Display Visible Light Photoreduction of CO₂ to CH₃OH Coupling with Oxidation of Amine to Imine

The photoreduction of carbon dioxide (CO₂) to valuable fuels is a promising strategy for the prevention of rising atmospheric levels of CO₂ and the depletion of fossil fuel reserves. However, most reported photocatalysts are only active in the ultraviolet region, which necessitates co-catalysts and sacrificial agents in the reaction systems, leading to an unsatisfied economy of the process in energy and atoms. In this research, a CuMo_xW_(1-x)O₄ solid solution was synthesized, characterized, and tested for the photocatalytic reduction of CO₂ in the presence of amines. The results revealed that the yield of CH₃OH from CO₂ was 1017.7 μmol/g under 24 h visible light irradiation using CuW_0.7Mo_0.3O₄ (x = 0.7) as the catalyst. This was associated with the maximum conversion (82.1%) of benzylamine to N-benzylidene benzylamine with high selectivity (>99%). These results give new insight into the photocatalytic reduction of CO₂ for valuable chemical products in an economic way.