A highly selective and recyclable sensor for the electroanalysis of phosphothioate pesticides using silver-doped ZnO nanorods arrays

Silver-doped ZnO nanorods (Ag/ZnO) arrays have in-situ grown onto indium tin oxide (ITO) via the one-pot hydrothermal route towards a highly selective and recyclable electroanalysis of phosphothioate pesticides (PTs) with phoxim (Phox) as a model. It was discovered that the Ag/ZnO arrays-modified electrode could obtain a steady and sharp electrochemical output of solid-state Ag/AgCl at a low potential (i.e., 0.12 V). More importantly, the achieved Ag/AgCl signals could decrease selectively induced by sulfide (S)-containing Phox by the specific Cl-S displacement reaction, which would trigger AgCl into non-electroactive Ag-Phox complex. The Ag/ZnO arrays-modified sensors present a linear range from 0.050 to 700.0 μM for the detection of Phox, with a limit of detection down to 0.010 μM. The practical applicability of the developed electroanalysis strategy was successfully employed to detect Phox in the tap water and cabbage samples. Moreover, the photocatalytic performances of the Ag/ZnO arrays were subsequently verified for the degradation of Phox, displaying the higher photocatalytic efficiency than pure ZnO nanorods. Besides, the as-developed sensor can allow for the recyclable detection of Phox by the Ag/ZnO-photocatalyzed removal of Phox after each of the detection cycles. Therefore, the sensors platform based on Ag/ZnO arrays can be expected to have potential for the electrochemical monitoring and photocatalytic degradation of toxic pesticides in the food and environmental fields.