Stable nitrogen isotope composition of NO_x of biomass burning in China

Owing to the local characteristics of stable nitrogen isotopes in nitrogen oxides (δ¹⁵N-NO_x) emitted from biomass burning, the lack of data on δ¹⁵N-NO_x values associated with biomass burning in China limits the use of this parameter in identifying and quantifying the sources of atmospheric nitrate (NO₃^-) and NO_x. The results showed that the δ¹⁵N-NO_x values of open burning and rural cooking stoves in China ranged from -3.7‰ to 3.1‰ and -11.9‰ to 1.5‰, respectively. The δ¹⁵N values of nine biomass fuel sources (δ¹⁵N-biomass) ranged from 0.1‰ to 4.1‰. Significant linear relationships between the δ¹⁵N-biomass values and δ¹⁵N-NO_x values of open burning (δ¹⁵N-NO_x = 1.1δ¹⁵N-biomass - 2.7; r² = 0.63; p < 0.05) and rural cooking stoves (δ¹⁵N-NO_x = 1.7δ¹⁵N-biomass - 9.8; r² = 0.72; p < 0.01) suggested that the variations in δ¹⁵N-NO_x values from biomass burning were mainly controlled by the biomass fuel source. The isotopic fractionation of nitrogen during the biomass burning process might have led to the higher δ¹⁵N-NO_x values from open burning in comparison to rural cooking stoves. By combining the δ¹⁵N-NO_x values of biomass burning with biomass burning emission inventory data, a model for calculating the δ¹⁵N-NO_x values of biomass burning in different regions of China was established, and the estimated δ¹⁵N-NO_x value of biomass burning at the national scale was -0.8 ± 1.2‰. But the limited δ¹⁵N-biomass values increase the uncertainty of model in national scale.