Removal of heavy metal(loid)s from aqueous solution by biogenic FeS-kaolin composite: Behaviors and mechanisms

In this work, a green adsorbent, biogenic FeS-kaolin composite (KL-FeS) was synthesized by sulfate-reducing bacteria (SRB) mediation, and its potential for Cd(II), Pb(II), Cu(II), Zn(II), As(III) and Sb(III) removal was evaluated. Among prepared composites, the KL-FeS synthesized at a concentration of 2 g/L kaolin performed a better removal efficiency on heavy metal(loid)s and the adsorption results followed the pseudo-second-order and Redlich-Peterson models, indicating that the adsorption was a hybrid chemical reaction-adsorption process. Additionally, the maximum adsorption capacities of Cd(II), Pb(II), Cu(II), Zn(II), As(III) and Sb(III) on KL-FeS in monocomponent system were 71.71, 133.54, 51.90, 54.41, 38.71 and 96.38 mg/g, respectively (pH = 5.0 ± 0.1, T = 25 °C). In addition, the increase of pH and ionic strength promoted the adsorption capacities of KL-FeS for metal-(loid)s. Moreover, FTIR, XPS and XRD analyses supported that surface complexation, hydrogen bonding, ion exchange, electrostatic interaction and chemical precipitation were predominately mechanisms involved in the adsorption process. Furthermore, KL-FeS displayed higher affinity for Pb(II), Sb(III) and Cu(II) in the multi-component system. This work highlighted the potential of biogenic FeS-kaolin composite for simultaneous removal of multiple heavy metal(loid)s under aerobic conditions.