Boosting Photocatalytic Performance of ZnO Nanowires via Building Heterojunction with g-C₃N₄

The development of a stable and highly active photocatalyst has garnered significant attention in the field of wastewater treatment. In this study, a novel technique involving a facile stirring method was devised to fabricate an array of g-C₃N₄/ZnO nanowire (ZnO NW) composites. Through the introduction of g-C₃N₄ to augment the generation of electron-hole pairs upon exposure to light, the catalytic efficacy of these composites was found to surpass that of the pristine ZnO NWs when subjected to simulated sunlight. The photocatalytic performance of a 20 mg·L^-1 methylene blue solution was found to be highest when the doping rate was 25 wt%, resulting in a degradation rate of 99.1% after 60 min. The remarkable enhancement in catalytic efficiency can be ascribed to the emergence of a captivating hetero-junction at the interface of g-C₃N₄ and ZnO NWs, characterized by a harmoniously aligned band structure. This alluring arrangement effectively curtailed charge carrier recombination, amplified light absorption, and augmented the distinct surface area, culminating in a notable boost to the photocatalytic prowess. These findings suggest that the strategic engineering of g-C₃N₄/ZnO NW heterostructures holds tremendous promise as a pioneering avenue for enhancing the efficacy of wastewater treatment methodologies.