Fast, accurate ranking of engineered proteins by target-binding propensity using structure modeling

Mol Ther. 2024 Jun 5;32(6):1687-1700. doi: 10.1016/j.ymthe.2024.04.003. Epub 2024 Apr 6.

Abstract

Deep-learning-based methods for protein structure prediction have achieved unprecedented accuracy, yet their utility in the engineering of protein-based binders remains constrained due to a gap between the ability to predict the structures of candidate proteins and the ability toprioritize proteins by their potential to bind to a target. To bridge this gap, we introduce Automated Pairwise Peptide-Receptor Analysis for Screening Engineered proteins (APPRAISE), a method for predicting the target-binding propensity of engineered proteins. After generating structural models of engineered proteins competing for binding to a target using an established structure prediction tool such as AlphaFold-Multimer or ESMFold, APPRAISE performs a rapid (under 1 CPU second per model) scoring analysis that takes into account biophysical and geometrical constraints. As proof-of-concept cases, we demonstrate that APPRAISE can accurately classify receptor-dependent vs. receptor-independent adeno-associated viral vectors and diverse classes of engineered proteins such as miniproteins targeting the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) spike, nanobodies targeting a G-protein-coupled receptor, and peptides that specifically bind to transferrin receptor or programmed death-ligand 1 (PD-L1). APPRAISE is accessible through a web-based notebook interface using Google Colaboratory (https://tiny.cc/APPRAISE). With its accuracy, interpretability, and generalizability, APPRAISE promises to expand the utility of protein structure prediction and accelerate protein engineering for biomedical applications.

Keywords: AAV engineering; AlphaFold; binder ranking; in silico screening; protein binders; protein design; protein engineering; protein structure prediction; receptor binding; receptor engagement.

MeSH terms

  • B7-H1 Antigen / chemistry
  • B7-H1 Antigen / genetics
  • B7-H1 Antigen / metabolism
  • COVID-19 / virology
  • Deep Learning
  • Dependovirus / genetics
  • Genetic Vectors / chemistry
  • Genetic Vectors / genetics
  • Genetic Vectors / metabolism
  • Humans
  • Models, Molecular
  • Protein Binding*
  • Protein Conformation
  • Protein Engineering* / methods
  • SARS-CoV-2* / genetics
  • SARS-CoV-2* / metabolism
  • Single-Domain Antibodies / chemistry
  • Single-Domain Antibodies / genetics
  • Single-Domain Antibodies / metabolism
  • Spike Glycoprotein, Coronavirus / chemistry
  • Spike Glycoprotein, Coronavirus / genetics
  • Spike Glycoprotein, Coronavirus / metabolism

Substances

  • Spike Glycoprotein, Coronavirus
  • spike protein, SARS-CoV-2
  • Single-Domain Antibodies
  • B7-H1 Antigen