Brazilin Actuates Ferroptosis in Breast Cancer Cells via p53/SLC7A11/GPX4 Signaling Pathway

Chin J Integr Med. 2024 Nov;30(11):1001-1006. doi: 10.1007/s11655-024-4104-y. Epub 2024 Apr 23.

Abstract

Objective: To investigate the mechanism of induction of ferroptosis by brazilin in breast cancer cells.

Methods: Breast cancer 4T1 cells were divided into 6 groups: control, brazilin 1/2 half maximal inhibitory concentration (IC50), IC50, 2×IC50, erastin (10 µg/mL) and capecitabine (10 µg/mL) groups. The effect of brazilin on the proliferation of 4T1 cells was detected by cell counting kit-8 assay, and the treatment dose of brazilin was screened. The effect of brazilin on the mitochondrial morphology of 4T1 cells, and the mitochondrial damage was evaluated under electron microscopy. The levels of Fe2+, reactive oxygen species (ROS), malondialdehyde (MDA), glutathione (GSH) and glutathione peroxidase 4 (GPX4) were estimated using various detection kits. The invasion and migration abilities of 4T1 cells were detected by scratch assay and transwell assay. The expressions levels of tumor protein p53, solute carrier family 7 member 11 (SLC7A11), GPX4 and acyl-CoA synthetase long-chain family member 4 (ACSL4) proteins were quantified by Western blot assay.

Results: Compared to the control group, the 10 (1/2 IC50), 20 (IC50) and 40 (2×IC50) µg/mL brazilin, erastin, and capecitabine groups showed a significant decrease in the cell survival rate, invasion and migration abilities, GSH, SLC7A11 and GPX4 protein expression levels, and mitochondrial volume and ridge (P<0.05), and a significant increase in the mitochondria membrane density, Fe2+, ROS and MDA levels, and p53 and ACSL4 protein expression levels (P<0.05).

Conclusions: Brazilin actuated ferroptosis in breast cancer cells, and the underlying mechanism is mainly associated with the p53/SLC7A11/GPX4 signaling pathway.

Keywords: Chinese medicine; brazilin; breast cancer; ferroptosis; p53/SLC7A11/GPX4 axis.

MeSH terms

  • Amino Acid Transport System y+* / metabolism
  • Animals
  • Benzopyrans
  • Breast Neoplasms* / drug therapy
  • Breast Neoplasms* / metabolism
  • Breast Neoplasms* / pathology
  • Cell Line, Tumor
  • Cell Movement / drug effects
  • Cell Proliferation / drug effects
  • Coenzyme A Ligases / metabolism
  • Female
  • Ferroptosis* / drug effects
  • Humans
  • Mice
  • Mitochondria / drug effects
  • Mitochondria / metabolism
  • Phospholipid Hydroperoxide Glutathione Peroxidase* / metabolism
  • Reactive Oxygen Species / metabolism
  • Signal Transduction* / drug effects
  • Tumor Suppressor Protein p53* / metabolism

Substances

  • Phospholipid Hydroperoxide Glutathione Peroxidase
  • Tumor Suppressor Protein p53
  • Amino Acid Transport System y+
  • brazilin
  • Reactive Oxygen Species
  • Coenzyme A Ligases
  • Slc7a11 protein, mouse
  • Benzopyrans