The impact of exchanging the light and heavy chains on the structures of bovine ultralong antibodies

Acta Crystallogr F Struct Biol Commun. 2024 Jul 1;80(Pt 7):154-163. doi: 10.1107/S2053230X2400606X. Epub 2024 Jul 1.

Abstract

The third complementary-determining regions of the heavy-chain (CDR3H) variable regions (VH) of some cattle antibodies are highly extended, consisting of 48 or more residues. These `ultralong' CDR3Hs form β-ribbon stalks that protrude from the surface of the antibody with a disulfide cross-linked knob region at their apex that dominates antigen interactions over the other CDR loops. The structure of the Fab fragment of a naturally paired bovine ultralong antibody (D08), identified by single B-cell sequencing, has been determined to 1.6 Å resolution. By swapping the D08 native light chain with that of an unrelated antigen-unknown ultralong antibody, it is shown that interactions between the CDR3s of the variable domains potentially affect the fine positioning of the ultralong CDR3H; however, comparison with other crystallographic structures shows that crystalline packing is also a major contributor. It is concluded that, on balance, the exact positioning of ultralong CDR3H loops is most likely to be due to the constraints of crystal packing.

Keywords: CDR3H; CDR3L; X-ray crystallography; antibodies; chain exchange; immunoglobulin; structural immunology; ultralong.

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Cattle
  • Complementarity Determining Regions* / chemistry
  • Crystallography, X-Ray
  • Immunoglobulin Fab Fragments* / chemistry
  • Immunoglobulin Heavy Chains* / chemistry
  • Immunoglobulin Light Chains* / chemistry
  • Immunoglobulin Light Chains* / genetics
  • Models, Molecular*
  • Protein Conformation

Substances

  • Immunoglobulin Heavy Chains
  • Immunoglobulin Light Chains
  • Complementarity Determining Regions
  • Immunoglobulin Fab Fragments