Giant Centella asiatica, a novel cultivar rich in madecassoside and asiaticoside, suppresses α‑melanocyte‑stimulating hormone‑induced melanogenesis through MC1R binding

Int J Mol Med. 2025 Jan;55(1):13. doi: 10.3892/ijmm.2024.5454. Epub 2024 Nov 8.

Abstract

The present study investigated the anti‑melanogenesis effects of Giant Centella asiatica (GCA), a new cultivator of Centella asiatica (CA) cataloged by the Korea Forest Service in 2022, and compared its efficacy with that of traditional CA. GCA has a high yield per unit area and enhanced antioxidant properties. The anti‑melanogenic effects of GCA were investigated using B16F10 melanoma cells and a 3D human skin‑equivalent model. Key molecular mechanisms were elucidated through western blotting, cAMP assays and molecular docking studies. Focus was addressed on the effect of GCA on skin whitening by comparing the ability of a GCA extract to inhibit melanin production in B16F10 melanoma cells and a 3D human skin‑equivalent model to that of CA. The results showed that the GCA extracts more effectively reduced melanin production, which was attributed to their higher content of two active components, madecassoside and asiaticoside. Further investigation revealed that GCA primarily inhibited melanogenesis through the PKA‑cAMP response element‑binding (CREB)‑microphthalmia‑associated transcription factor (MITF) axis, a key regulatory pathway in melanin synthesis. Notably, the present study, to the best of our knowledge, is the first to demonstrate that madecassoside and asiaticoside, the two principal compounds in GCA, directly bound to MC1R, which contributed to the significant skin‑whitening effects. Moreover, GCA reduced melanin production in a 3D human skin‑equivalent model, showing efficacy within a complex skin environment. These results demonstrated the superior effectiveness of GCA to that of CA for skin anti‑melanogenesis, indicating its potential as a promising natural material for targeting pigmentation disorders.

Keywords: 3D human skin‑equivalent model; Centella asiatica; anti-melanogenesis; giant Centella asiatica; melanocytes; α‑MSH.

MeSH terms

  • Animals
  • Cell Line, Tumor
  • Centella* / chemistry
  • Humans
  • Melanins* / biosynthesis
  • Melanins* / metabolism
  • Melanogenesis
  • Melanoma, Experimental / drug therapy
  • Melanoma, Experimental / metabolism
  • Melanoma, Experimental / pathology
  • Mice
  • Molecular Docking Simulation
  • Plant Extracts* / chemistry
  • Plant Extracts* / pharmacology
  • Receptor, Melanocortin, Type 1* / metabolism
  • Skin Pigmentation / drug effects
  • Triterpenes* / chemistry
  • Triterpenes* / pharmacology
  • alpha-MSH* / metabolism
  • alpha-MSH* / pharmacology

Substances

  • Triterpenes
  • Melanins
  • madecassoside
  • asiaticoside
  • alpha-MSH
  • Plant Extracts
  • Receptor, Melanocortin, Type 1
  • Centella asiatica extract

Grants and funding

The present study was supported by BOBSNU Co. Ltd., ASK Company Co. Ltd., Brain Korea 21 Plus Program of the Department of Agricultural Biotechnology, Seoul National University and the Bio and Medical Technology Development Program of the National Research Foundation (NRF), funded by the Korean government (MSIT) (grant no. 2020M3H1A1073304). The present study was also supported by the NRF of Korea (NRF) grant funded by the Korea government (MSIT) (grant no. RS-2024-00333238).