This study demonstrates the potential for reusing commercial activated carbon (CAC) to capture high molecular weight and high-boiling point volatile organic compounds (HBPVOCs). Through comprehensive characterization and performance evaluation, we found that CAC effectively adsorbs Butyl Cellosolve (BCS), a common industrial solvent, with adsorption capacity increasing with pressure. The adsorption process follows pseudo-first-order kinetics, indicating single-layer physical adsorption. Additionally, the study highlights the recyclability of CAC, as desorption and subsequent analysis revealed minimal changes in pore structure, maintaining a significant portion of its original BET value. These findings suggest that CAC is not only effective for BCS adsorption but also sustainable for repeated use, offering an efficient and eco-friendly solution for managing industrial HBPVOCs.