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Page 1
On the catalytic mechanism of human ATP citrate lyase.
Fan F, Williams HJ, Boyer JG, Graham TL, Zhao H, Lehr R, Qi H, Schwartz B, Raushel FM, Meek TD. Fan F, et al. Biochemistry. 2012 Jun 26;51(25):5198-211. doi: 10.1021/bi300611s. Epub 2012 Jun 15. Biochemistry. 2012. PMID: 22657152
An internal equilibrium preorganizes the enzyme-substrate complex for hydride tunneling in choline oxidase.
Fan F, Gadda G. Fan F, et al. Biochemistry. 2007 May 29;46(21):6402-8. doi: 10.1021/bi700255v. Epub 2007 May 2. Biochemistry. 2007. PMID: 17472346
The hydride transfer reaction catalyzed by choline oxidase under irreversible regime, i.e., at saturating oxygen, was shown in a recent study to occur quantum mechanically within a highly preorganized active site, with the reactive configuration for hydride tunneling being minima …
The hydride transfer reaction catalyzed by choline oxidase under irreversible regime, i.e., at saturating oxygen, was shown in a recent stud …
Mechanistic studies of choline oxidase with betaine aldehyde and its isosteric analogue 3,3-dimethylbutyraldehyde.
Fan F, Germann MW, Gadda G. Fan F, et al. Biochemistry. 2006 Feb 14;45(6):1979-86. doi: 10.1021/bi0517537. Biochemistry. 2006. PMID: 16460045
The chemical mechanism for the oxidation of choline catalyzed by choline oxidase was recently elucidated by using kinetic isotope effects [Fan, F., and Gadda, G. (2005) J. Am. Chem. Soc. 127, 2067-2074]. In this study, the oxidation of betaine aldehyde has been inve …
The chemical mechanism for the oxidation of choline catalyzed by choline oxidase was recently elucidated by using kinetic isotope effects [ …
3,085 results