Functionalization of Screen-Printed Electrodes with Grape Stalk Waste Extract-Assisted Synthesized Silver and Gold Nanoparticles: Perspectives of Electrocatalytically Enhanced Determination of Uranyl Ion and Other Heavy Metals Ions

Recently, nanotechnology and nanoparticles (NPs) such as AgNPs and AuNPs have become important in analytical chemistry due to their great potential to improve the performance of electrochemical sensors. In this work, Ag and Au nanoparticles have been synthesized using a green route in which a grape stalk waste extract is used as a reducing agent to obtain metallic nanoparticles. These NPs were used to customize the surface of commercial screen-printed electrodes (SPCNFEs). The spin-coating method was used to modify commercial SPCNFEs under a nitrogen atmosphere. The resulting electrodes were used in a determination study of Cd(II), Pb(II), and U(VI) with differential pulse anodic stripping voltammetry (DPASV). The customized green AgNPs and AuNPs electrodes presented higher sensitivity and electroanalytical performance than the non-modified SPCNFE. The results showed that the best analytical parameters were obtained with the green, silver nanoparticle SPCNFEs, with a LOD of 0.12 μg L^-1 for Pb(II), which is a lower value compared to the most restrictive regulation guidelines. Additionally, the U(VI) ion was successfully determined using the developed G-AgNPs-SPCNFE in spiked tap water, showing comparable results with the ICP-MS technique.