JR & ER - Eng. PC PDF
JR & ER - Eng. PC PDF
As you are proceeding for Deepawali Vacations, you are looking forward to free time, fun and
frolic with family and friends. I, on the behalf of my department, wish you all the joy and
happiness in this festival period.
Deepawali is a festival of lights. We lighten lamps to drive away the darkness of moonless
night of Deepawali. Do not forget, it is also a very crucial period for you when you can pull out
some time for your revision. Devote your mornings and afternoons to academics (self-study)
while evening should be reserved for pure enjoyment. Do not plan any study in evening
duration, just enjoy freely and have a good time if you have studied properly in the morning.
As you lighten the lamps of Deepawali, also lighten the lamp of knowledge in your heart. I am
offering you unlighted deepaks in the form of Chemistry problems. Lighten them with the fire
of your mind, and solve them all to celebrate true deepawali.
May your interest in your subject intensify. May you learn to work hard with consistency. May
you always maintain your focus. May you be true to yourself. May Ma Saraswati bless you
with all that is desirable. This is a blessing from my heart.
With affection,
Shishir Mittal,
VP(SW) and HoD (Chemistry),
Resonance.
ORGANIC CHEMISTRY
IUPAC NOMENCLATURE
Instruction :
1. The test is of 1 hour duration.
2. The Test Booklet consists of 30 questions. The maximum marks are 120.
3. Each question is allotted 4 (four) marks for correct response.
4. Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each
question. ¼ [one fourth (–1)] marks will be deducted for indicating incorrect response of each
question.
________________________________________________________________________________________
Straight Objective Type
This section contains 30 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, out
of which ONLY ONE is correct. Each question carry (4, – 1) Marks.
________________________________________________________________________________________
1. What is correct about methyl butane and 2-methyl pentane.
(1) Both have same empirical formula. (2) Both have same molecular formula.
(3) Both have same general formula. (4) Both have same number of carbon atoms
2. Which of the following has CnH2n general formula ?
5. N compound is :
H
(1) Unsaturated homocyclic (2) Aromatic heterocyclic
(3) Saturated heterocyclic (4) Unsaturated heterocylic
(1) 4-Methyl-2,6-dibromo-2-chloro-5-fluoroheptane
(2) 4-Methyl-2-chloro-2,6-dibromo-5-fluoroheptane
(3) 2,6-Dibromo-2-chloro-5-fluoro-4-methylheptane
(4) 4-Methyl-6-chloro-2,6-dibromo-3-fluoroheptane
7. The correct IUPAC name of the following compound is :
H OCH3 NO2
Cl — C — C — C — Et
CH3 Br H
(1) 2-Bromo-1-chloro-3-ethyl-2-methoxy-1-methyl-3-nitropropane
(2) 3-Bromo-2-chloro-3-methoxy-4-nitrohexane
(3) 3-Bromo-2-chloro-4-ethyl-3-methoxy-4-nitrobutane
(4) 4-Bromo-5-chloro-4-methoxy-3-nitrohexane
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8. In the structure word root changes by replacing the value of R. What will be R.
Br
7
6
2 4
3 6 5 1
(3) 1 (4) 3
5 4 2
10. Correct IUPAC name of the following compound is :
Br
(1) (2)
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17. Structure of the 2,2-Dimethylbutane dioic acid :
O O
(3) C–O–CH2–CH2–CH3 (4) C–O–CH(CH3)2
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26. The IUPAC name of is :
OCH3
(1) (2)
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ISOMERISM STRUCTURAL & PRACTICAL ORGANIC CHEMISTRY
Instruction :
1. The test is of 1 hour duration.
2. The Test Booklet consists of 30 questions. The maximum marks are 120.
3. Each question is allotted 4 (four) marks for correct response.
4. Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each
question. ¼ [one fourth (–1)] marks will be deducted for indicating incorrect response of each
question.
________________________________________________________________________________________
Straight Objective Type
This section contains 30 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, out
of which ONLY ONE is correct. Each question carry (4, – 1) Marks.
________________________________________________________________________________________
1. In position isomers :
(1) Nature of Functional group changed (2) Length of parent or side chain changed
(3) Position of multiple bond changed (4) None of these
2. The structures (CH3)2CHCH2Br and CH3(CH2)3Br shows :
(1) position isomers (2) chain isomerism
(3) functional isomerism (4) None of these
3. Which of the following are chain isomer :
(1) Hexane and Heptane (2) 1,1-Dichloroethane and 1,2-Dichloroethane
(3) 2-Methyl pentane and 3-Methyl pentane (4) Pentane and neopentane
4. 1,1-Dimethylcyclopropane and 1,2-Dimethylcyclopropane are :
(1) Positional isomer (2) Metamer
(3) Functional isomer (4) Chain isomer
5. Diethylether and Methylpropyl ether are
(1) Positional isomers (2) Functional isomers
(3) Metamers (4) Chain isomers
6. The isomerism exhibited by alkyl cyanide and alkyl isocyanide is :
(1) Functional isomerism (2) Positional isomerism
(3) Chain isomerism (4) Metamerism
11. How many cyclic alcohols are possible with molecular formula C4H8O.
12. Which can give only 3 monochloro structure isomers on reaction with chlorine in presence of light ?
(1) 2-Methyl propane (2) 2-Methyl butane
(3) 3-Methyl pentane (4) 3-Ethyl pentane
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13. The total number of monochloro products (structural) formed.
Cl2 / h
16. product
17. Ozonolysis of which unsaturated hydrocarbon of the following will give aldehyde and ketone both ?
(1) 2, 3-Dimethyl but-2-ene (2) 1, 2, 3, 4-Tetramethylcyclopenta-1,3-diene
(3) But-2-yne (4) 2-Methylbut-2-ene
O
18. CH2=CH–CH=CH–CH3 3
Zn,H O
Products.
2
19. An organic compound C8H12 adds two moles of H2 per mole of hydrocarbon. It undergoes reductive
ozonolysis to give Butane-1,4-dial only. What is the structure of hydrocarbon ?
(1) (2)
(3) (4)
20. A hydrocarbon C9H16 consumes only mole of H2 in the presence of nickel as catalyst. On ozonolysis,
the hydrocarbon produces cyclohexanone and acetone. The hydrocarbon is
CH3 CH2 CH3
CH3
C C
CH2 CH3 CH3
(1) (2) (3) (4)
CH3 CH2CH3
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23. Benzaldehyde and acetone can be distinguished by
(1) Mulliken Baker test (2) Fehling solution
(3) Iodoform test (4) Ninhydrin test
24. Phenol and Benzoic acid can be distinguished by
(1) FeCl3 test (2) Mollisch test (3) Hinsberg test (4) Tollen's test
NaHCO
28. 3
X gas
NaHCO
Ph-CH2-SO3H 3
Y gas
X and Y are respectively
14 14
(1) CO 2 , SO2 (2) CO2, CO 2 (3) CO2, SO2 (4) CO2, SO3
30. Which compound can not give Prussian blue colour in lassaigne test ?
(1) CH3–NH–CH3 (2) Pyridine (3) NH2–NH2 (4) Aniline
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ELECTRONIC EFFECT & APPLICATION (GOC)
Instruction :
1. The test is of 1 hour duration.
2. The Test Booklet consists of 30 questions. The maximum marks are 120.
3. Each question is allotted 4 (four) marks for correct response.
4. Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each
question. ¼ [one fourth (–1)] marks will be deducted for indicating incorrect response of each
question.
________________________________________________________________________________
Straight Objective Type
This section contains 30 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, out
of which ONLY ONE is correct. Each question carry (4, – 1) Marks.
________________________________________________________________________________
1. Which of the following groups has the highest + effect.
(1) –COO (2) CH3 CH2 – (3) (CH3 )2 CH– (4) (CH3 )3 C–
2. In which of the following correct stability order is shown :
(1) < (2) <
7. Which of the following orders is correct for heat of hydrogenation of these compounds ?
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10. Arrange the following in increasing order of stability
, ,
(1) III < II < I (2) I < II < III (3) III < I < II (4) II < I < III
11. Which is the most stable resonating structure.
(1) (2) (3) (4)
(1) (2)
N N
(3) (4) &
S N
(ii) and
(iii) and
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20. Which of the following cations is most stable ?
21. In which of the following carbocation rearrangement takes place most rapidly ?
22.
CH3—CH2—NH2 (CH3)2NH
(P) (Q) (R) (S)
(1) P > S > R > Q (2) R > S > Q > P (3) P > R > Q > S (4) S > R > Q > P
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28. Compare acidic strength of the following compound.
(1) (2)
(3) (4)
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STEREOISOMERS
Instruction :
1. The test is of 1 hour duration.
2. The Test Booklet consists of 30 questions. The maximum marks are 120.
3. Each question is allotted 4 (four) marks for correct response.
4. Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each
question. ¼ [one fourth (–1)] marks will be deducted for indicating incorrect response of each
question.
________________________________________________________________________________
Straight Objective Type
This section contains 30 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, out
of which ONLY ONE is correct. Each question carry (4, – 1) Marks.
________________________________________________________________________________
1. Types of geometrical isomerism shown at point X, Y and Z of the following compound respectively are :
X Y Z X Y Z
(1) cis cis trans (2) cis trans trans
(3) trans cis cis (4) cis trans cis
2. Which of the following compounds does not have any geometrical isomer ?
4. A natural occurring substance has the constitution shown below. How many isomers may have this
constitution ?
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7. Which of the following compounds having E-configuration –
CH3
CH3O CH 2–Br CH
C C CH3
(1) OHC CH2 –NO2 (2) C=C=C=C
CH2–CH2–CH3
I II III IV
(1) I, II and III are meso compounds (2) II and III are enantiomers
(3) I, III and IV are enantiomer (4) III and IV are identical
14. Which of the following compound is meso isomers ?
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16. Which of the following statements about the relationships of the structure (P), (Q) , (R) and (S) is
incorrect ?
18. Which of the following properties are different for (R)-2-bromo butane and (S)-2-bromobutane
(1) Boiling point (2) Melting point (3) Density (4) Configuration
19. Which of the following compounds do not have the plane of symmetry ?
20. Which of the following statements are INCORRECT about these molecules ?
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25. Metamer of compound B is :
B:
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ANSWER KEY
PHYSICAL CHEMISTRY
MOLE CONCEPT
1. (3) 2. (1) 3. (1) 4. (3) 5. (3)
6. (4) 7. (3) 8. (1) 9. (2) 10. (3)
11. (1) 12. (3) 13. (3) 14. (3) 15. (2)
PERIODIC TABLE
36. (4) 37. (4) 38. (2) 39. (3) 40. (2)
41. (1) 42. (1) 43. (3) 44. (3) 45. (1)
CHEMICAL EQUILIBRIUM
46. (1) 47. (1) 48. (2) 49. (3) 50. (3)
51. (1) 52. (2) 53. (3) 54. (4) 55. (4)
56. (3) 57. (2) 58. (3) 59. (3) 60. (1)
61. (2) 62. (1) 63. (2) 64. (3) 65. (2)
IONIC EQUILIBRIUM-3
66. (1) 67. (2) 68. (2) 69. (4) 70. (3)
CHEMICAL BONDING
71. (2) 72. (4) 73. (4) 74. (2) 75. (2)
76. (1) 77. (1) 78. (3) 79. (3) 80. (3)
81. (2) 82. (3) 83. (4) 84. (3) 85. (3)
COORDINATION COMPOUNDS
101. (1) 102. (3) 103. (1) 104. (1) 105. (3)
106. (1) 107. (2) 108. (4) 109. (4) 110. (2)
111. (2) 112. (2) 113. (4) 114. (3) 115. (3)
s-BLOCK ELEMENTS
116. (4) 117. (2) 118. (2) 119. (3) 120. (4)
SURFACE CHEMISTRY
121. (4) 122. (1) 123. (4) 124. (2) 125. (2)
126. (2) 127. (2) 128. (1) 129. (1) 130. (2)
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ORGANIC CHEMISTRY
IUPAC NOMENCLATURE
1. (3) 2. (3) 3. (2) 4. (3) 5. (4)
6. (3) 7. (2) 8. (4) 9. (3) 10. (2)
11. (2) 12. (3) 13. (4) 14. (4) 15. (2)
16. (1) 17. (1) 18. (4) 19. (1) 20. (1)
21. (2) 22. (2) 23. (3) 24. (2) 25. (3)
26. (2) 27. (3) 28. (2) 29. (3) 30. (3)
STEREOISOMERS
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