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23 pages, 7079 KiB  
Article
The Impact of pH on Fouling and Related Physicochemical Properties of Skim Milk Concentrate during Heat Treatment Using a Laboratory-Scale Fouling Rig
by Tara R. Murphy, Eoin W. Finnegan, Justyna Tarapata, Tom F. O’Callaghan and James A. O’Mahony
Foods 2024, 13(19), 3100; https://doi.org/10.3390/foods13193100 (registering DOI) - 28 Sep 2024
Abstract
The objective of this study was to investigate the effect of pH (6.1, 6.3, 6.5, and 6.7) on heat-induced changes in concentrated skim milk as related to fouling in heat exchangers. Skim milk (30%, w/w, total solids) was recirculated in [...] Read more.
The objective of this study was to investigate the effect of pH (6.1, 6.3, 6.5, and 6.7) on heat-induced changes in concentrated skim milk as related to fouling in heat exchangers. Skim milk (30%, w/w, total solids) was recirculated in a laboratory-scale fouling rig at an initial target temperature of 85 °C for 90 min to simulate thermal processing and preheating of evaporated liquid concentrate feeds in dairy processing. This study investigated key changes in relevant physicochemical properties, such as viscosity, particle size, and sedimentation, as major contributors to fouling at lower pHs (6.1 and 6.3). Additionally, protein aggregation and calcium phosphate precipitation were identified as significant contributors to fouling deposits. Possible strategies to mitigate fouling were determined, including optimizing pH and adjusting heat treatment parameters to minimize protein denaturation and mineral deposition. The findings indicate that carefully controlling pH and processing parameters can greatly enhance the efficiency of milk concentration by evaporation and tailor finished product quality. Moreover, this study showed that monitoring of CIP solutions for protein content and turbidity provides valuable information on the intensity of fouling and the efficiency of cleaning. Full article
(This article belongs to the Section Dairy)
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21 pages, 6003 KiB  
Article
Assessment of Energy Recovery Potential in Urban Underground Utility Tunnels: A Case Study
by Tong Wei, Mingyue Fan, Zijun Xu, Weijun Li, Zhaolin Gu and Xilian Luo
Buildings 2024, 14(10), 3113; https://doi.org/10.3390/buildings14103113 (registering DOI) - 28 Sep 2024
Viewed by 34
Abstract
Underground spaces contain abundant geothermal energy, which can be recovered for building ventilation, reducing energy consumption. However, current research lacks a comprehensive quantitative assessment of its energy recovery. This research evaluates the energy recovery potential of the Xingfu Forest Belt Urban Underground Utility [...] Read more.
Underground spaces contain abundant geothermal energy, which can be recovered for building ventilation, reducing energy consumption. However, current research lacks a comprehensive quantitative assessment of its energy recovery. This research evaluates the energy recovery potential of the Xingfu Forest Belt Urban Underground Utility Tunnels. Field experiments revealed a 7 °C temperature difference in winter and a 2.5 °C reduction during the summer-to-autumn transition. A computational fluid dynamics (CFD) model was developed to assess the impact of design and operational factors such as air exchange rates on outlet temperatures and heat exchange efficiency. The results indicate that at an air change rate of 0.5 h−1, the tunnel outlet temperature dropped by 10.5 °C. A 200 m tunnel transferred 8.7 × 1010 J of heat over 30 days, and a 6 m × 6 m cross-sectional area achieved 1.1 × 1011 J of total heat transfer. Increasing the air exchange rate and cross-sectional area reduces the inlet–outlet temperature difference while enhancing heat transfer capacity. However, the optimal buried depth should not exceed 8 m due to cost and safety considerations. This study demonstrates the potential of shallow geothermal energy as an eco-friendly and efficient solution for enhancing building ventilation systems. Full article
(This article belongs to the Special Issue Renewable Energy and Sustainable Building Design)
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21 pages, 2129 KiB  
Article
A Novel Approach to Enhancing the Determination of Primary Indicators in Non-Idealised Absorption Chillers
by Gábor L. Szabó
Energies 2024, 17(19), 4858; https://doi.org/10.3390/en17194858 - 27 Sep 2024
Viewed by 175
Abstract
The accurate optimisation of absorption chillers is often impeded by idealised models that overlook system interactions and machine complexities. This study introduces a validated mathematical description for predicting the primary indicators of non-idealised absorption chillers, accounting for factors such as the electrical work [...] Read more.
The accurate optimisation of absorption chillers is often impeded by idealised models that overlook system interactions and machine complexities. This study introduces a validated mathematical description for predicting the primary indicators of non-idealised absorption chillers, accounting for factors such as the electrical work of the Solution Circulation Pump, entropy changes within the refrigerant cycle, and exergy losses. Validation against 13 years of data (2008–2021) from the University of Debrecen’s absorption chiller indicated close agreement, with deviations within acceptable limits. The use of a solution heat exchanger shifted cooling indicators towards their minima. Sensitivity analyses indicated that a 2.5% reduction in condenser temperature increased COP by 41.3% and Cooling Exergetic Efficiency by 15.5%, while a 2.5% reduction in the Heat Fraction Factor improved both by 34%. Adjusting absorber temperature and Heat Fraction Factor down by 2.5%, alongside a 2.5% rise in generator temperature, resulted in a 100.8% increase in COP and a 52.8% boost in Cooling Exergetic Efficiency. These insights provide a solid foundation for future optimisation strategies in real-life absorption chiller systems. Full article
(This article belongs to the Section K: State-of-the-Art Energy Related Technologies)
23 pages, 6576 KiB  
Article
Fractional-Order Modeling of Heat and Moisture Transfer in Anisotropic Materials Using a Physics-Informed Neural Network
by Yaroslav Sokolovskyy, Kazimierz Drozd, Tetiana Samotii and Iryna Boretska
Materials 2024, 17(19), 4753; https://doi.org/10.3390/ma17194753 - 27 Sep 2024
Viewed by 191
Abstract
Mathematical models of heat and moisture transfer for anisotropic materials, based on the use of the fractional calculus of integro-differentiation, are considered because such two-factor fractal models have not been proposed in the literature so far. The numerical implementation of mathematical models for [...] Read more.
Mathematical models of heat and moisture transfer for anisotropic materials, based on the use of the fractional calculus of integro-differentiation, are considered because such two-factor fractal models have not been proposed in the literature so far. The numerical implementation of mathematical models for determining changes in heat exchange and moisture exchange is based on the adaptation of the fractal neural network method, grounded in the physics of processes. A fractal physics-informed neural network architecture with a decoupled structure is proposed, based on loss functions informed by the physical process under study. Fractional differential formulas are applied to the expressions of non-integer operators, and finite difference schemes are developed for all components of the loss functions. A step-by-step method for network training is proposed. An algorithm for the implementation of the fractal physics-informed neural network is developed. The efficiency of the new method is substantiated by comparing the obtained numerical results with numerical approximation by finite differences and experimental data for particular cases. Full article
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21 pages, 5049 KiB  
Article
A Novel Fuel-Based CO2 Transcritical Cycle for Combined Cooling and Power Generation on Hypersonic Aircrafts
by Yijian He, Lisong Wang, Jiaqi Dong and Qifei Chen
Energies 2024, 17(19), 4853; https://doi.org/10.3390/en17194853 - 27 Sep 2024
Viewed by 142
Abstract
This study focuses on the great challenges for combined cooling and power supply on hypersonic aircrafts. To address the issues of low thermal efficiency and high fuel consumption of heat sink by the existing CO2 supercritical Brayton cycle, a novel fuel-based CO [...] Read more.
This study focuses on the great challenges for combined cooling and power supply on hypersonic aircrafts. To address the issues of low thermal efficiency and high fuel consumption of heat sink by the existing CO2 supercritical Brayton cycle, a novel fuel-based CO2 transcritical cooling and power (FCTCP) system is constructed. A steady-state simulation model is built to investigate the impacts of combustion chamber wall temperatures and fuel mass flow rates on the FCTCP system. Thermal efficiency of the CO2 transcritical cycle reaches 25.2~32.8% under various combustion chamber wall outlet temperatures and endothermic pressures. Compared with the supercritical Brayton cycle, the thermal efficiency of novel system increases by 54.5~80.9%. It is found from deep insights into the thermodynamic results that the average heat transfer temperature difference between CO2 and fuel is effectively reduced from 153.4 K to 16 K by split cooling of the fuel in the FCTCP system, which greatly enhances the matching of CO2–fuel heat exchange temperatures and reduces the heat exchange loss of the system. Thermodynamic results also show that, in comparison to the supercritical Brayton cycle, the cooling capacity and power generation per unit mass flow rate of working fluid in the FCTCP system increased by 75.4~80.8% and 12.9~51.6%, respectively. The FCTCP system exhibits a substantial performance improvement, significantly enhancing the key characteristic index of the combined cooling and power supply system. This study presents a novel approach to solving the challenges of cooling and power supply in hypersonic aircrafts under limited fuel heat sink conditions, laying the groundwork for further exploration of thermal management technologies of hypersonic aircrafts. Full article
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24 pages, 5666 KiB  
Article
Design of a Steady-State Adjustment Method and Sensitivity Analysis for an ORC System with Plate Heat Exchangers
by Lantian Ji, Xiao Wang, Zhilong He and Ziwen Xing
Appl. Sci. 2024, 14(19), 8728; https://doi.org/10.3390/app14198728 - 27 Sep 2024
Viewed by 183
Abstract
Because of its low concentration and low energy in an organic Rankine cycle (ORC) system, more than 50% of low-grade thermal energy with a temperature below 300 °C is not taken seriously. The relationship between changeable working condition parameters and operating parameters is [...] Read more.
Because of its low concentration and low energy in an organic Rankine cycle (ORC) system, more than 50% of low-grade thermal energy with a temperature below 300 °C is not taken seriously. The relationship between changeable working condition parameters and operating parameters is typically not taken into account in a model while studying ORC systems. It is insufficient to analyze the system performance changes solely on changes in the performance parameters of the heat exchangers. Furthermore, a model perspective of the system control solution is absent from the steady-state control of the system when the heat source varies. In this paper, we created a system model for the application scenario of a 100–200 kW ORC system with brazed plate heat exchangers in order to address the aforementioned issues using MATLAB R2016b. Additionally, a sensitivity analysis of the system was conducted based on heat exchangers of performance variations. In addition, a modeling computation and adjustment scheme were put forth to guarantee that the system could continue to produce steady power production even when the temperature of the heat source fluctuated. Preliminary results showed that the system’s internal parameters included its evaporation pressure and condensation temperature. An increase in evaporation pressure will reduce the mass flow rate and heat flux of an evaporator, thus reducing the heat transfer coefficient. The two-phase region of the evaporator accounted for the highest proportion, of 70.22%, and continued to increase to 75.83%, followed by the supercooling region, and gradually decreasing. The utilization rate of the evaporator decreased from 74.85% to 38.32%. The system output power increased first and then decreased, with a maximum value of 153.11 kW. The system efficiency increased from 5.74% to 11.04%. The increase in condensation temperature increased the proportion of the two-phase region and the superheating region, and the mass flow rate did not change much. The increase in heat flux increased the heat transfer coefficient from 1721.31 W/(m2·K) to 2374.77 W/(m2·K), and the utilization rate of the evaporator decreased from 70.56% to 51.91%. The aforementioned change rules were used in the building of the steady-state regulation model to balance out the changes in the generating power as the heat source temperature increased. The model output was cross-checked and validated against pertinent experimental test literature data. The results of this research can serve as a valid and useful guide for ORC system design and practical applications. Full article
(This article belongs to the Section Applied Thermal Engineering)
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35 pages, 17147 KiB  
Article
Utilizing Wastewater Tunnels as Thermal Reservoirs for Heat Pumps in Smart Cities
by Fredrik Skaug Fadnes and Mohsen Assadi
Energies 2024, 17(19), 4832; https://doi.org/10.3390/en17194832 - 26 Sep 2024
Viewed by 274
Abstract
The performance of heat pump systems for heating and cooling heavily relies on the thermal conditions of their reservoirs. This study introduces a novel thermal reservoir, detailing a 2017 project where the Municipality of Stavanger installed a heat exchanger system on the wall [...] Read more.
The performance of heat pump systems for heating and cooling heavily relies on the thermal conditions of their reservoirs. This study introduces a novel thermal reservoir, detailing a 2017 project where the Municipality of Stavanger installed a heat exchanger system on the wall of a main wastewater tunnel beneath the city center. It provides a comprehensive account of the system’s design, installation, and performance, and presents an Artificial Neural Network (ANN) model that predicts heat pump capacity, electricity consumption, and outlet temperature across seasonal variations in wastewater temperatures. By integrating domain knowledge with the ANN, this study demonstrates the model’s capability to detect anomalies in heat pump operations effectively. The network also confirms the consistent performance of the heat exchangers from 2020 to 2024, indicating minimal fouling impacts. This study establishes wastewater heat exchangers as a safe, effective, and virtually maintenance-free solution for heat extraction and rejection. Full article
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23 pages, 5482 KiB  
Article
Developing a Chained Simulation Method for Quantifying Cooling Energy in Buildings Affected by the Microclimate of Avenue Trees
by Bryon Flowers and Kuo-Tsang Huang
Atmosphere 2024, 15(10), 1150; https://doi.org/10.3390/atmos15101150 - 25 Sep 2024
Viewed by 238
Abstract
This paper introduces a methodology aimed at bridging the gap between building energy simulation and urban climate modeling. A coupling method was developed through the Building Control Virtual Test Bed (BCVTB) and applied to a case study in Taipei City, Taiwan, to address [...] Read more.
This paper introduces a methodology aimed at bridging the gap between building energy simulation and urban climate modeling. A coupling method was developed through the Building Control Virtual Test Bed (BCVTB) and applied to a case study in Taipei City, Taiwan, to address the microclimate factors of street trees crucial to cooling energy consumption. The use of the Urban Weather Generator for weather file modification revealed a 0.63 °C average air temperature disparity. The coupling method emphasized the importance of accurate wind speed and convective heat transfer coefficients (CHTCs) on building surfaces in determining cooling energy. The results indicated that elevated CHTC values amplify heat exchange, with higher wind velocities playing a crucial role in heat dissipation. The presence of street trees was found to significantly reduce heat flux penetration, leading to a reduction in building surface temperatures by as much as 9.5% during hot months. The cooling energy was lowered by 16.7% in the BCVTB simulations that included trees compared to those without trees. The EnergyPlus-only simulations underestimated the cooling energy needs by approximately 9.3% during summer months. This research offers valuable insights into the complex interactions between buildings and their environments. The results highlight the importance of trees and shading in mitigating the heat island effect and improving energy-efficient urban planning. Full article
(This article belongs to the Section Biometeorology and Bioclimatology)
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26 pages, 6642 KiB  
Article
Performance of the Earth Explorer 11 SeaSTAR Mission Candidate for Simultaneous Retrieval of Total Surface Current and Wind Vectors
by Adrien C. H. Martin, Christine P. Gommenginger, Daria Andrievskaia, Petronilo Martin-Iglesias and Alejandro Egido
Remote Sens. 2024, 16(19), 3556; https://doi.org/10.3390/rs16193556 - 24 Sep 2024
Viewed by 486
Abstract
Interactions between ocean surface currents, winds and waves at the atmosphere-ocean interface are key controls of lateral and vertical exchanges of water, heat, carbon, gases and nutrients in the global Earth System. The SeaSTAR satellite mission concept proposes to better quantify and understand [...] Read more.
Interactions between ocean surface currents, winds and waves at the atmosphere-ocean interface are key controls of lateral and vertical exchanges of water, heat, carbon, gases and nutrients in the global Earth System. The SeaSTAR satellite mission concept proposes to better quantify and understand these important dynamic processes by measuring two-dimensional fields of total surface current and wind vectors with unparalleled spatial and temporal resolution (1 × 1 km2 or finer, 1 day) and unmatched precision over one continuous wide swath (100 km or more). This paper presents a comprehensive numerical analysis of the expected performance of the Earth Explorer 11 (EE11) SeaSTAR mission candidate in the case of idealised and realistic 2D ocean currents and wind fields. A Bayesian framework derived from satellite scatterometry is adapted and applied to SeaSTAR’s bespoke inversion scheme that simultaneously retrieves total surface current vectors (TSCV) and ocean surface vector winds (OSVW). The results confirm the excellent performance of the EE11 SeaSTAR concept, with Root Mean Square Errors (RMSE) for TSCV and OSVW at 1 × 1 km2 resolution consistently better than 0.1 m/s and 0.4 m/s, respectively. The analyses highlight some performance degradation in some relative wind directions, particularly marked at near range and low wind speeds. Retrieval uncertainties are also reported for several variations around the SeaSTAR baseline three-azimuth configuration, indicating that RMSEs improve only marginally (by ∼0.01 m/s for TSCV) when including broadside Radial Surface Velocity or broadside dual-polarisation data in the inversion. In contrast, our results underscore (a) the critical need to include broadside Normalised Radar Cross Section data in the inversion; (b) the rapid performance degradation when broadside incidence angles become steeper than 20° from nadir; and (c) the benefits of maintaining ground squint angle separation between fore and aft lines-of-sight close to 90°. The numerical results are consistent with experimental performance estimates from airborne data and confirm that the EE11 SeaSTAR concept satisfies the requirements of the mission objectives. Full article
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9 pages, 2392 KiB  
Proceeding Paper
Experimental Evaluation of Thermal Performance in Shell and Tube Heat Exchangers Using Al₂O₃-γ Nanofluids
by Shahid Iqbal, Muhammad Faisal Naveed, Manzar Masud, Adnan Tariq, Taimoor Kausar, Zohaib Nasir and Moazzam Ali Babar
Eng. Proc. 2024, 75(1), 13; https://doi.org/10.3390/engproc2024075013 - 24 Sep 2024
Viewed by 161
Abstract
Shell and tube heat exchangers (H.Xs) are being used broadly in the generation of power, refrigeration, nuclear, chemical, and petroleum industries due to their high cooling and heating capacity. In this research paper, an experimental test bench for a shell and tube H.X [...] Read more.
Shell and tube heat exchangers (H.Xs) are being used broadly in the generation of power, refrigeration, nuclear, chemical, and petroleum industries due to their high cooling and heating capacity. In this research paper, an experimental test bench for a shell and tube H.X was fabricated according to the standard. This study aimed to test the thermal performance of shell and tube H.Xs using Al2O3-γ nanofluid with different concentrations in counter flow configurations. Nanoparticles of 12 nm of size and 99% purity were used in this investigation. These nanoparticles were dispersed in distilled water to prepare nanofluids at three different concentrations: 0.11%, 0.22%, and 0.34%. Nanofluids of different concentrations were heated and passed through H.X tubes while water was passed through the shell side. The experiments were performed at three different flow rates: 6, 8, and 10 L per minute (L/min). It was observed from the experimentation that nanofluid has higher efficiency as compared to simple distilled water. Experimental investigations showed higher values of overall heat transfer coefficient (U), convective heat transfer coefficient (h), and heat transfer rate (Q˙) at 0.22%, noted as 33.33%, 48%, and 30%, respectively. The lowest value for U was noted 47% for distilled water. The hydrodynamic and thermal boundary layers were also determined, and when the flow rate increased it led to thinning of the thermal boundary layer and improved heat transfer; however, increased concentrations of nanoparticles thickened the boundary layer by increasing viscosity and boosting thermal conductivity (k) simultaneously. It was revealed that the best concentration for maximizing heat transfer was 0.22%. The findings show that heat transmission efficiency was improved at both 0.11% and 0.22% of nanofluids compared to simple distilled water; when the concentration was raised to 0.34%, the results decreased due to increasing viscosity. Therefore, there is a need to precisely adjust the nanoparticle loading rate for maximum heat transfer enhancement without affecting fluid properties. Full article
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18 pages, 4744 KiB  
Article
Heat Transfer Enhancement in a 3D-Printed Compact Heat Exchanger
by Marcin Kruzel, Tadeusz Bohdal and Krzysztof Dutkowski
Energies 2024, 17(18), 4754; https://doi.org/10.3390/en17184754 - 23 Sep 2024
Viewed by 552
Abstract
The study describes experimental data on thermal tests during the condensation of HFE7100 refrigerant in a compact heat exchanger. The heat exchanger was manufactured using the additive 3D printing in metal. The material is AISI 316L steel. MPCM slurry was used as the [...] Read more.
The study describes experimental data on thermal tests during the condensation of HFE7100 refrigerant in a compact heat exchanger. The heat exchanger was manufactured using the additive 3D printing in metal. The material is AISI 316L steel. MPCM slurry was used as the heat exchanger coolant, and water was used as the reference medium. The refrigerant was condensed on a bundle of circular tubes made of steel with an internal/external diameter of di/de = 2/3 mm, while a mixture of water and phase change materials as the coolant flowed through the channels. Few studies consider the heat exchange in condensation using phase change materials; furthermore, there is also a lack of description of heat exchange in small-sized exchangers printed from metal. Most papers deal with computer research, including flow simulations of heat exchange. The study describes the process of heat exchange enhancement using the phase transition of coolant. Experimental data for the mPCM slurry coolant flow was compared to the data of pure water flow as a reference liquid. The tests were carried out under the following thermal and flow conditions: G = 10–450 [kg m−² s−1], q = 2000–25,000 [W m²], and ts = 30–40 [°C]. The conducted research provided many quantities describing the heat exchange in compact heat exchangers, including heat exchanger heat power, heat exchange coefficient, and heat exchange coefficients for working media. Based on these factors, the thermal performance of the heat exchanger was described. External characteristics include the value of the thermal power and the heat exchange coefficient as a function of the mass flow density of the working medium and the average logarithmic temperature difference. The performance of the heat exchanger was presented as the dependencies of the heat exchange coefficients on the mass flux density and the heat flux density on the heat exchange surface. The thickness of the refrigerant’s condensate film was also determined. Furthermore, a model was proposed to determine the heat exchange coefficient value for the condensing HFE7100 refrigerant on the outer surface of a bundle of smooth tubes inside a compact heat exchanger. According to experimental data, the calculation results were in good agreement with each other, with a range of 25%. These data can be used to design mini condensers that are widely used in practice. Full article
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23 pages, 2789 KiB  
Article
Thermodynamic Comparative Analysis of Cascade Refrigeration System Pairing R744 with R404A, R448A and R449A with Internal Heat Exchanger: Part 2—Exergy Characteristics
by Min-Ju Jeon and Joon-Hyuk Lee
Energies 2024, 17(18), 4708; https://doi.org/10.3390/en17184708 - 21 Sep 2024
Viewed by 336
Abstract
The cascade refrigeration systems (CRS) used in hypermarkets and supermarkets, which are used by many people, have been employing R744 for the low-temperature cycle (LTC) and R404A for the high-temperature cycle (HTC) due to environmental and public safety issues. However, the use of [...] Read more.
The cascade refrigeration systems (CRS) used in hypermarkets and supermarkets, which are used by many people, have been employing R744 for the low-temperature cycle (LTC) and R404A for the high-temperature cycle (HTC) due to environmental and public safety issues. However, the use of R404A is limited due to its high GWP, and therefore research on alternative refrigerants is necessary. Nevertheless, there is no detailed study in the literature that compares and analyzes the three refrigerants for practical design by applying R744 for LTC and R404A, R448A, and R449A for HTC in CRS. Therefore, this study aims to provide data for the practical detailed design of an alternative system to R744/R404A CRS. Under standard conditions, we analyzed how the exergy destruction rate (EDR) and exergy efficiency (EE) of the system and the EDR of each component change when the important factors affecting CRS (degree of superheating (DSH), degree of subcooling (DSC), and internal heat exchanger (IHX) efficiency of HTC, DSH of LTC, condensation temperature (CT), evaporation temperature (ET), cascade evaporation temperature (CET), and temperature difference of CHX) are varied over a wide range. The main conclusions are as follows. (1) Under the given constant conditions, the smallest change in system EDR based on R448A is DSH of HTC (decreased by 0.07–0.1 kW), followed by IHX of HTC (decreased by 0.12–0.3 kW), DSH of LTC (increased by 0.19–0.25 kW), DSC of HTC (decreased by 0.59–0.69 kW), temperature difference of CHX (increased by 1.57–1.83 kW), CET (decreased and then increased by 0.67–4.43 kW), CT (increased by 1.49–3.9 kW), ET (decreased by 2.39–4.61 kW). (2) The highest change rate of system EE based on R448A is CET (increased and then decreased by 1.38–8.28%), followed by temperature difference of CHX (decreased by 2.96–3.16%), ET (increased and then decreased by 0.63–2.75%), DSC of HTC (increased by 1.26–1.34%), CT (increased and then decreased by 0.24–1.12%), IHX of HTC (increased by 0.11–1.02%), DSH of LTC (decreased by 0.35–0.49%), and DSH of HTC (increased by 0.14–0.19%). Full article
(This article belongs to the Section J: Thermal Management)
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34 pages, 8988 KiB  
Review
Strategies for Mitigating Phosphoric Acid Leaching in High-Temperature Proton Exchange Membrane Fuel Cells
by Zhongming Xu, Nanjie Chen, Sheng Huang, Shuanjin Wang, Dongmei Han, Min Xiao and Yuezhong Meng
Molecules 2024, 29(18), 4480; https://doi.org/10.3390/molecules29184480 - 20 Sep 2024
Viewed by 1040
Abstract
High-temperature proton exchange membrane fuel cells (HT-PEMFCs) have become one of the important development directions of PEMFCs because of their outstanding features, including fast reaction kinetics, high tolerance against impurities in fuel, and easy heat and water management. The proton exchange membrane (PEM), [...] Read more.
High-temperature proton exchange membrane fuel cells (HT-PEMFCs) have become one of the important development directions of PEMFCs because of their outstanding features, including fast reaction kinetics, high tolerance against impurities in fuel, and easy heat and water management. The proton exchange membrane (PEM), as the core component of HT-PEMFCs, plays the most critical role in the performance of fuel cells. Phosphoric acid (PA)-doped membranes have showed satisfied proton conductivity at high-temperature and anhydrous conditions, and significant advancements have been achieved in the design and development of HT-PEMFCs based on PA-doped membranes. However, the persistent issue of HT-PEMFCs caused by PA leaching remains a challenge that cannot be ignored. This paper provides a concise overview of the proton conduction mechanism in HT-PEMs and the underlying causes of PA leaching in HT-PEMFCs and highlights the strategies aimed at mitigating PA leaching, such as designing crosslinked structures, incorporation of hygroscopic nanoparticles, improving the alkalinity of polymers, covalently linking acidic groups, preparation of multilayer membranes, constructing microporous structures, and formation of micro-phase separation. This review will offer a guidance for further research and development of HT-PEMFCs with high performance and longevity. Full article
(This article belongs to the Special Issue Materials in Fuel Cell: Design and Electrochemical Application)
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12 pages, 5100 KiB  
Article
Determination of the Temperature Development in a Borehole Heat Exchanger Field Using Distributed Temperature Sensing
by David Bertermann and Oliver Suft
Energies 2024, 17(18), 4697; https://doi.org/10.3390/en17184697 - 20 Sep 2024
Viewed by 427
Abstract
The use of geothermal borehole heat exchangers (BHEs) in combination with ground-source heat pumps represents an important part of shallow geothermal energy production, which is already used worldwide and becoming more and more important. Different measurement techniques are available to examine a BHE [...] Read more.
The use of geothermal borehole heat exchangers (BHEs) in combination with ground-source heat pumps represents an important part of shallow geothermal energy production, which is already used worldwide and becoming more and more important. Different measurement techniques are available to examine a BHE field while it is in operation. In this study, a field with 54 BHEs up to a depth of 120 m below ground level was analyzed using fiber optic cables. A distributed temperature sensing (DTS) concept was developed by equipping several BHEs with dual-ended hybrid cables. The individual fiber optics were collected in a distributor shaft, and multiple measurements were carried out during active and inactive operation of the field. The field trial was carried out on a converted, partly retrofitted, residential complex, “Lagarde Campus”, in Bamberg, Upper Franconia, Germany. Groundwater and lithological changes are visible in the depth-resolved temperature profiles throughout the whole BHE field. Full article
(This article belongs to the Section H2: Geothermal)
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27 pages, 13088 KiB  
Article
Effects of Surface Layer Physics Schemes on the Simulated Intensity and Structure of Typhoon Rai (2021)
by Thi-Huyen Hoang, Ching-Yuang Huang and Thi-Chinh Nguyen
Atmosphere 2024, 15(9), 1140; https://doi.org/10.3390/atmos15091140 - 20 Sep 2024
Viewed by 374
Abstract
The influences of surface layer (SL) physics schemes on the simulated intensity and structure of Typhoon Rai (2021) are investigated using the WRF model. Numerical experiments using different SL physics schemes—revised MM5 scheme (MM5), Eta similarity scheme (CTL), and Mellor–Yamada–Nakanishi–Niino scheme (MYNN)—are conducted. [...] Read more.
The influences of surface layer (SL) physics schemes on the simulated intensity and structure of Typhoon Rai (2021) are investigated using the WRF model. Numerical experiments using different SL physics schemes—revised MM5 scheme (MM5), Eta similarity scheme (CTL), and Mellor–Yamada–Nakanishi–Niino scheme (MYNN)—are conducted. The results show that the intensity forecast of Typhoon Rai is largely influenced by SL physics schemes, while its track forecast is not significantly affected. All three experiments can successfully capture the movement of Rai, while CTL provides better intensity simulation compared to the other two experiments. The higher ratio of enthalpy exchange coefficient to drag coefficient (CK/CD) in CTL than MM5 and MYNN leads to significantly increased surface enthalpy fluxes, which are crucial for the typhoon intensification of the former. To explore the influence of SL physics on the structural evolution of the typhoon, the azimuthal-mean angular momentum (AM) budget is utilized. The results indicate that asymmetric eddy terms may also largely contribute to the AM tendencies, which are relatively more comparable in the weaker TC for MM5, compared to the stronger TC with the dominant symmetric mean terms for CTL. Furthermore, the extended Sawyer–Eliassen (SE) equation is solved to quantify the transverse circulations of the typhoon induced by different forcing sources for CTL and MM5. The SE solution indicates that the transverse circulation above and within the boundary layer is predominantly induced by diabatic heating and turbulent friction, respectively, for both CTL and MM5, while all other physical forcing terms are relatively insignificant for the induced transverse circulation for CTL, except for the large contribution from the eddy forcing in the upper-tropospheric outflow for MM5. With the stronger connective heating in the eyewall and boundary-layer radial inflow, the linear SE analysis agrees much better with the nonlinear simulation for CTL than MM5. Full article
(This article belongs to the Section Meteorology)
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