Search Results (343)

(R)-2-Amino-1-hydroxyethylphosphonic acid 2 was prepared by hydrolytic kinetic resolution of rac-diethyl oxiran-2-ylphosphonate followed by reaction with benzylamine, acid hydrolysis, catalytic hydrogenolysis, and anion-exchange chromatography. Recrystallization from water-ethanol gave pure 2, which was characterized by IR, ¹H NMR, ¹³C NMR, ³¹P NMR, polarimetry, elemental microanalysis, high-resolution mass spectrometry, and single-crystal X-ray diffraction. The acid 2 crystallized in the orthorhombic noncentrosymmetric space group P2₁2₁2₁ with cell parameters a = 6.303 (2) Å, b = 7.104 (2) Å, c = 11.627 (3) Å. The X-ray crystal structure confirmed the (R)-configuration of 2 and revealed that 2 is zwitterionic in the solid state, with extensive intermolecular hydrogen bonding between the hydroxyl, ammonium cation, and phosphonate anion groups. Full article

Among the more than 60 sources observed in the first two years of operations, IXPE addressed four magnetars, neutron stars believed to host ultra-strong magnetic fields. We report here the main implication coming from IXPE measurements for the physics of magnetars. Polarimetric observations confirmed the expectations of high polarization degrees, up to ≈$80\%$, values which have not been detected in any other source so far, providing further proof (independent from the P-$\dot{P}$ estimate) that magnetars host indeed ultra-magnetized neutron stars. Polarization measurements also indicate that softer X-rays likely come from surface regions where the overlying atmosphere underwent magnetic condensation. The agreement of the phase-dependent polarization angle with a simple rotating vector model strongly supports the presence of vacuum birefringence around the star. Full article

X-ray polarization, which now can be measured by the Imaging X-ray Polarimetry Explorer (IXPE), is a new probe of jets in the supermassive black hole systems of active galactic nuclei (AGNs). Here, we summarize IXPE observations of radio-loud AGNs that have been published thus far. Blazars with synchrotron spectral energy distributions (SEDs) that peak at X-ray energies are routinely detected. The degree of X-ray polarization is considerably higher than at longer wavelengths. This is readily explained by energy stratification of the emission regions when electrons lose energy via radiation as they propagate away from the sites of particle acceleration as predicted in shock models. However, the 2–8 keV polarization electric vector is not always aligned with the jet direction as one would expect unless the shock is oblique. Magnetic reconnection may provide an alternative explanation. The rotation of the polarization vector in Mrk421 suggests the presence of a helical magnetic field in the jet. In blazars with lower-frequency peaks and the radio galaxy Centaurus A, the non-detection of X-ray polarization by IXPE constrains the X-ray emission mechanism. Full article

The Imaging X-ray Polarimetry Explorer (IXPE) has confirmed that X-ray polarimetry is a valuable tool in astronomy, providing critical insights into the emission processes and the geometry of compact objects. IXPE was designed to be sensitive in the 2–8 keV energy range for three primary reasons: (1) celestial X-ray sources are bright within this range, (2) the optics are effective, and (3) most sources across various classes were expected to exhibit some level of polarization. Indeed, IXPE is a great success, and its discoveries are necessitating the revision of many theoretical models for numerous sources. However, one of IXPE’s main limitations is its relatively narrow energy band, coupled with rapidly declining efficiency. In this paper, we will demonstrate the benefits of devising a mission focused on a broader energy band (0.1–79 keV). This approach leverages current technologies that align well with theoretical expectations and builds on the successes of IXPE. Full article

Radiation from X-ray pulsars (XRPs) was expected to be strongly linearly polarized owing to a large difference in their ordinary and extraordinary mode opacities. The launch of IXPE allowed us to check this prediction. IXPE observed a dozen X-ray pulsars, discovering pulse-phase dependent variation of the polarization degree (PD) and polarization angle (PA). Although the PD showed rather erratic profiles resembling flux pulse dependence, the PA in most cases showed smooth variations consistent with the rotating vector model (RVM), which can be interpreted as a combined effect of vacuum birefringence and dipole magnetic field structure at a polarization-limiting (adiabatic) radius. Application of the RVM allowed us to determine XRP geometry and to confirm the free precession of the NS in Her X-1. Deviations from RVM in two bright transients led to the discovery of an unpulsed polarized emission likely produced by scattering off the accretion disk wind. Full article

Pulsars (PSRs) and Pulsar Wind Nebulae (PWNe) form some of the most interesting high-energy astrophysical systems. Their prominent synchrotron emission makes them ideal candidates for polarimetry. Here, after briefly summarizing the scientific rationale underpinning the importance of their polarimetric studies, we review the current status and achievements obtained by the IXPE mission. For the first time, we have space- and phase-resolved X-ray data that allow us to set constraints on the geometry and level of turbulence of the magnetic field which, in turn, can help us to better understand which acceleration and radiation model(s) might be at work in these systems. Interestingly, PWNe show a large variety in terms of polarization degree that might indicate key physical differences, still to be further investigated. Full article

Low-mass X-ray binaries hosting weakly magnetized neutron stars (NS-LMXBs) are among the brightest sources in the X-ray sky. Since 2021, the Imaging X-ray Polarimetry Explorer (IXPE) has provided new measurements of the X-ray polarization of these sources. IXPE observations have revealed that most NS-LMXBs are significantly polarized in the X-rays, providing unprecedented insight into the geometry of their accretion flow. In this review paper, we summarize the first results obtained by IXPE on NS-LMXBs, the emerging trends within each class of sources (atoll/Z), and possible physical interpretations. Full article

Metasurfaces can flexibly manipulate electromagnetic waves by engineering subwavelength structures, which have attracted enormous attention in holography, cloaking, and functional multiplexing. For structures with n-fold (n > 2) rotational symmetry, they have been utilized to realize broadband and high-efficiency wavefront manipulation with generalized Pancharatnam–Berry phase, whereas spin-selective wavefront manipulation is still a challenge limited by their symmetrical spin–orbit interactions. Here, we demonstrate the spin-selective wavefront manipulations with generalized Pancharatnam–Berry phase in the range of 560–660 nm with a metal–insulator–metal metasurface consisting of the chiral C3 logarithmic spiral nanostructures. As a proof of concept, two deflectors and a bifocal metalens are designed. This configuration may provide a platform for various applications in polarimetry, polarization-selective images, and nonlinear optical responses. Full article

Drs. Weisskopf and Ramsey were the original Principal and Deputy Principal Investigators of the Imaging X-ray Polarimetry Explorer (IXPE). They outline the path to the development of IXPE and discuss the technical and programmatic history that led up to the mission, a partnership between the Italian Space Agency and NASA, and the first fully dedicated to imaging X-ray polarimetry in the 2–8 keV band. An admittedly biased, as seen through the eyes of the original and Deputy Principal Investigators, technical overview of the development of the historical and critical scientific instrumentation is provided. The outstanding, and often paradigm-shifting results are presented in the papers following this one. Full article

Drone-based imaging polarimetry is a valuable new tool for the remote sensing of the polarization characteristics of the Earth’s surface. After briefly reviewing two earlier drone-polarimetric studies, we present here the results of our drone-polarimetric campaigns, in which we measured the reflection–polarization patterns of greenhouses. From the measured patterns of the degree and angle of linear polarization of reflected light, we calculated the measure (plp) of polarized light pollution of glass surfaces. The knowledge of polarized light pollution is important for aquatic insect ecology, since polarotactic aquatic insects are the endangered victims of artificial horizontally polarized light sources. We found that the so-called Palm House of a botanical garden has only a low polarized light pollution, 3.6% ≤ plp ≤ 13.7%, while the greenhouses with tilted roofs are strongly polarized-light-polluting, with 24.8% ≤ plp ≤ 40.4%. Similarly, other tilted-roofed greenhouses contain very high polarized light pollution, plp ≤ 76.7%. Under overcast skies, the polarization patterns and plp values of greenhouses practically only depend on the direction of view relative to the glass surfaces, as the rotationally invariant diffuse cloud light is the only light source. However, under cloudless skies, the polarization patterns of glass surfaces significantly depend on the azimuth direction of view and its angle relative to the solar meridian because, in this case, sunlight is the dominant light source, rather than the sky. In the case of a given direction of view, those glass surfaces are the strongest polarized-light-polluting, from which sunlight and/or skylight is reflected at or near Brewster’s angle in a nearly vertical plane, i.e., with directions of polarization close to horizontal. Therefore, the plp value is usually greatest when the sun shines directly or from behind. The plp value of greenhouses is always the smallest in the green spectral range due to the green plants under the glass. Full article

This study develops a structure for mapping native vegetation in a transition area between the Brazilian Cerrado and the Atlantic Forest from integrated spatial information of Sentinel-1 and Sentinel-2 satellites. Most studies use integrated data to improve classification accuracy in adverse atmospheric conditions, in which optical data have many errors. However, this method can also improve classifications carried out in landscapes with favorable atmospheric conditions. The use of Sentinel-1 and Sentinel-2 data can increase the accuracy of mapping algorithms and facilitate visual interpretation during sampling by providing more parameters that can be explored to differentiate land use classes with complementary information, such as spectral, backscattering, polarimetry, and interferometry. The study area comprises the Lobo Reservoir Hydrographic Basin, which is part of an environmental conservation unit protected by Brazilian law and with significant human development. LULC were classified using the random forest deep learning algorithm. The classifying attributes were backscatter coefficients, polarimetric decomposition, and interferometric coherence for radar data (Sentinel-1), and optical spectral data, comprising bands in the red edge, near-infrared, and shortwave infrared (Sentinel-2). The attributes were evaluated in three settings: SAR and optical data in separately settings (C1 and C2, respectively) and in an integrated setting (C3). The study found greater accuracy for C3 (96.54%), an improvement of nearly 2% compared to C2 (94.78%) and more than 40% in relation to C1 (55.73%). The classification algorithm encountered significant challenges in identifying wetlands in C1, but performance improved in C3, enhancing differentiation by stratifying a greater number of classes during training and facilitating visual interpretation during sampling. Accordingly, the integrated use of SAR and optical data can improve LULC mapping in tropical regions where occurs biomes interface, as in the transitional Brazilian Cerrado and Atlantic Forest. Full article

Active galactic nuclei (AGNs), either radio-quiet or radio-loud, had never been observed in X-ray polarized light until the advent of the Imaging X-ray Polarimetry Explorer (IXPE) in the end of 2021. This satellite opened a new observational window for studying supermassive black holes and their complex environment. In this regard, radio-quiet AGNs are probably better targets than radio-loud objects to probe accretion processes due to the lack of synchrotron emission from jets that can dilute the polarized signal from the central engine. Their relatively clean environment not only allows to detect and measure the X-ray polarization originating from the hot corona responsible for X-ray emission, but also to assess the geometry of the media immediately surrounding the supermassive black hole. Such geometrical measurements work just as well for characterizing the corona morphology in pole-on AGNs as it does for determining the three-dimensional shape of the circumnuclear cold obscurer (the so-called torus) in edge-on AGNs. In this review paper, we will return to each of the observations made by IXPE so far in the field of radio-quiet AGNs and highlight the fundamental contribution of X-ray polarimetry to our understanding of how light is emitted and how matter is shaped around supermassive black holes. Full article

The generation of terahertz radiation via laser-induced plasma from two-color femtosecond pulses in air has been extensively studied due to its broad emission spectrum and significant pulse energy. However, precise control over the temporal properties of these ultra-broadband terahertz pulses, as well as the measurement of their polarization state, remain challenging. In this study, we review our latest findings on these topics and present additional results not previously reported in our earlier works. First, we investigate the impact of chirping on the fundamental wave and the effect of manipulating the phase difference between the fundamental wave and the second-harmonic wave on the properties of generated terahertz pulses. We demonstrate that we can tune the time shape of terahertz pulses, causing them to reverse polarity or become bipolar by carefully selecting the correct combination of chirp and phase. Additionally, we introduce a novel technique for polarization characterization, termed terahertz unipolar polarimetry, which utilizes a weak probe beam and avoids the systematic errors associated with traditional methods. This technique is effective for detecting polarization-structured terahertz beams and the longitudinal component of focused terahertz beams. Our findings contribute to the improved control and characterization of terahertz radiation, enhancing its application in fields such as nonlinear optics, spectroscopy, and microscopy. Full article

Polarimetry is used to determine the Stokes parameters of a laser beam. Once all four $S_{0,1,2,3}$ parameters are determined, the state of polarisation is established. Upon reflection of a laser beam with the defined S polarisation state, the directly measured S parameters can be used to determine the optical properties of the surface, which modify the S-state upon reflection. Here, we use polarimetry for the determination of surface anisotropies related to the birefringence and dichroism of different materials, which have a common feature of linear patterns with different alignments and scales. It is shown that polarimetry in the back-reflected light is complementary to ellipsometry and four-polarisation camera imaging; experiments were carried out using a microscope. Full article

Measurements of magnetic fields near seismic sources during solar flares are vital for understanding the dynamics of solar activity. We used spectropolarimetric observations of the X17.2/4B solar flare on 28 October 2003, over a wavelength interval of 43 Å, including the D3, D2, D1, and Ni I 5892.88 Å lines, to analyze the Stokes I ± V profiles. Effective magnetic fields within 0.5–1.5 kG were measured in the D1, D2, and D3 lines at different flare locations, with the photospheric Ni I 5892.88 Å line showing a weaker field of below 0.5 kG. The D3 line showed rapid plasma descents of up to 11 km/s, in contrast to the slower velocities within 2.3 km/s observed in other lines. The differing amplitudes in the I + V and I − V profiles indicated potential non-Zeeman polarization effects. Secondary Stokes V peaks were also detected up to 8 Å from the D3 emission core. Significant altitudinal inhomogeneity in the magnetic field strengths was detected, possibly indicating the local magnetic collapse, facilitating the Lorentz-force driven mechanism of the seismic source excitation. Full article