Phosgenite
Phosgenite | |
---|---|
![]() Crystal of phosgenite from the Monteponi Mine, Iglesias, Sardinia, Italy (size: 3.0 x 3.0 x 2.5 cm) | |
Allgemein | |
Kategorie | Carbonate minerals |
Formula (repeating unit) | (PbCl)2CO3 |
IMA symbol | Pho[1] |
Strunz classification | 5.BE.20 |
Crystal system | Tetragonal |
Crystal class | Ditetragonal dipyramidal (4/mmm) H-M symbol: (4/m 2/m 2/m) |
Space group | P4/mbm |
Unit cell | a = 8.16 Å, c = 8.883(6) Å; Z = 4 |
Identification | |
Color | Pale yellow to yellowish brown, pale brown, smoky brown, smoky violet, colorless, pale rose, gray, yellowish gray, pale green |
Crystal habit | Short prismatic crystals, granular, massive |
Cleavage | Distinct on {001} and {110}, indistinct on {100} |
Fracture | Conchoidal |
Tenacity | Sectile, flexible perpendicular to {001} |
Mohs scale hardness | 2–3 |
Luster | Adamantine |
Streak | White |
Diaphaneity | Transparent to translucent |
Specific gravity | 6.12 – 6.15 |
Optical properties | Uniaxial (+); anomalously biaxial if strained |
Refractive index | nω = 2.118 nε = 2.145 |
Birefringence | δ = 0.027 |
Pleochroism | Weakly pleochroic with O – reddish and E – greenish in thick sections. |
Ultraviolet fluorescence | Fluoresces yellow under LW and SW UV |
Solubility | Soluble in dilute nitric acid with effervescence, decomposes slowly in cold water |
References | [2][3][4][5] |
Phosgenite is a rare mineral consisting of lead carbonate chloride, (PbCl)2CO3. The tetragonal crystals are prismatic or tabular in habit: they are usually colorless and transparent, and have a brilliant adamantine lustre. Sometimes the crystals have a curious helical twist about the tetrad or principal axis. The hardness is 3 and the specific gravity 6.3. The mineral is rather sectile, and consequently was earlier known as corneous lead, (German Hornblei).[6]
Name and occurrence
[edit]![](http://upload.wikimedia.org/wikipedia/commons/thumb/a/a0/Phosgenite-RoyalOntarioMuseum-Jan18-09.jpg/220px-Phosgenite-RoyalOntarioMuseum-Jan18-09.jpg)
The name phosgenite was given by August Breithaupt in 1820, after phosgene, carbon oxychloride, because the mineral contains the elements carbon, oxygen, and chlorine.[6]
It was found associated with anglesite and matlockite in cavities within altered galena in a lead mine at Cromford, near Matlock: hence its common name cromfordite.[7] Crystals are also found in galena at Monteponi near Iglesias in Sardinia, and near Dundas in Tasmania.[6] It has also been reported from Laurium, Greece; Tarnowitz, Poland; the Altai district, Siberia; the Touissit mine, near Oujda, Morocco; Sidi Amor ben Salem, Tunisia; Tsumeb, Namibia; Broken Hill, New South Wales; and Boleo, near Santa Rosalía, Baja California Sur. In the US it has been reported from the Terrible mine, Custer County, Colorado; the Stevenson-Bennett mine, Organ Mountains, Doña Ana County, New Mexico; and the Mammoth mine, Tiger, Pinal County, Arizona.[3]
Crystals of phosgenite, and also of the corresponding bromine compound PbBr2CO3, have been prepared artificially.[6]
See also
[edit]- Barstowite, another lead chloride carbonate
References
[edit]- ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
- ^ Mineralienatlas
- ^ a b Handbook of Mineralogy
- ^ Mindat.org
- ^ Webmineral data
- ^ a b c d public domain: Spencer, Leonard James (1911). "Phosgenite". In Chisholm, Hugh (ed.). Encyclopædia Britannica. Vol. 21 (11th ed.). Cambridge University Press. p. 474. One or more of the preceding sentences incorporates text from a publication now in the
- ^ "Phosgenite and Matlockite in Derbyshire (Part 1). T. Bridges, M. E. Smith. Journal of the Russell Society Volume 1, No. 2, p.7–14, 1983 Retrieved on 2011-01-11
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