According to https://www.mediawiki.org/wiki/Extension:MobileFrontend#Setup_a_skin one could set
$wgMFDefaultSkinClass = 'SkinVector';
to have MobileFrontend use Vector.
However, setting that configuration (mediawiki 1:1.35.0~rc.3-1) with multiple MobileFrontent versions, fail with:
PHP Fatal error: Uncaught Error: Cannot use object of type RequestContext as array in /usr/share/mediawiki/includes/skins/Skin.php:157 tack trace: #0 /var/lib/mediawiki/extensions/MobileFrontend/includes/MobileFrontendHooks.php(60): Skin->__construct(Object(RequestContext)) #1 /var/lib/mediawiki/extensions/MobileFrontend/includes/MobileFrontendHooks.php(127): MobileFrontendHooks::getDefaultMobileSkin(Object(RequestContext), Object(GlobalVarConfig)) #2 /usr/share/mediawiki/includes/HookContainer/HookContainer.php(320): MobileFrontendHooks::onRequestContextCreateSkin(Object(RequestContext), NULL) #3 /usr/share/mediawiki/includes/HookContainer/HookContainer.php(131): MediaWiki\\HookContainer\\HookContainer->callLegacyHook('RequestContextC...', Array, Array, Array) #4 /usr/share/mediawiki/includes/HookContainer/HookRunner.php(3221): MediaWiki\\HookContainer\\HookContainer->run('RequestContextC...', Array) #5 /usr/share/mediawiki/includes/context/RequestContext.php(402): MediaWiki\\HookContainer\\HookRunner->onRequestContextCreateSkin( in /usr/share/mediawiki/includes/skins/Skin.php on line 157