STANDARD
STANDARD
BRITISH STANDARD
Specification for
Urea-formaldehyde
(UF) foam systems
suitable for thermal
insulation of cavity
walls with masonry or
concrete inner and
outer leaves
UDC 678.6524121:692.232.2:699.86
BS 5617:1985
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BS 5617:1985
The following bodies were also represented in the drafting of the standard,
through subcommittees and panels:
Building Employers Confederation
Eurisol (UK) Association of Manufacturers of Mineral Insulation Fibres
Welwyn Hall Research Association
Amendments issued since publication
Amd. No.
Date of issue
Kommentare
BS 5617:1985
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Contents
Page
Committees responsible
Inside front cover
Foreword
ii
0
Introduction
1
1
Scope
1
2
Definitions
1
3
Property requirements
1
4
Processing requirements
2
5
Shelf-life limitations of foam system components
3
Appendix A Method for determination of effective density
4
Appendix B Method for determination of linear shrinkage
4
Appendix C Method for determination of water absorption
5
Appendix D Method for determination of wet density
5
Appendix E Method for determination of foam system gel time
6
Appendix F Method for determination of foam system stability
7
Appendix G Method for determination of foam system appearance
7
Appendix H Method for determination of solid resin yield
7
Appendix J Method for determination of free formaldehyde
content of UF resin
7
Appendix K Method for determination of water tolerance
of UF resin
8
Appendix L Method for determination of total acidity of
foaming hardeners
9
Appendix M Method for determination of resin viscosity by
the break time method
9
Figure 1 Test sample for effective density and shrinkage tests
4
Figure 2 Determination of foam system gel time
6
Table 1 Property requirements: type tests
2
Table 2 Property requirements: quality control tests
2
Table 3 Limiting values and permissible deviations for
foam system components
2
Table 4 UF resin: shelf-life limitations
3
Table 5 Water tolerance conversion
9
Publications referred to
Inside back cover
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BS 5617:1985
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Foreword
This revision of BS 5617, which has been prepared under the direction of the
Plastics Standards Committee, supersedes BS 5617:1978 which is withdrawn.
The successful insulation of external cavity walls still relies on two standards,
i.e. this standard, which specifies requirements for the foam systems which would
be suitable for the application and the second standard, BS 5618 which is the code
of practice used by the installation contractor to satisfactorily install suitable
foam systems.
Accordingly, BS 5617 addresses the interface between the foam system supplier
and the installation contractor, and BS 5618 that between the installation
contractor and his client.
In this revision the foam systems have been restricted to use in cavities with
masonry or concrete inner and outer leaves, requirements relating to the
activities of the installation contractor have been removed (and placed as
recommendations in the revision of BS 5618), and the property requirements
made more stringent.
Attention is drawn to the fact that the urea-formaldehyde resins used for foam
system production have a limited shelf-life: during storage they will ultimately
undergo changes and become unsuitable for use. It is therefore important that the
manufacturers recommendations with regard to storage should be observed if the
maximum storage life is to be obtained.
Also foam systems differ according to the source of supply of the UF resin and the
foaming hardener, and certain properties listed in Table 2 to Table 4 have
therefore been given tolerances rather than specific values.
A British Standard does not purport to include all the necessary provisions of a
contract. Users of British Standards are responsible for their correct application.
Compliance with a British Standard does not of itself confer immunity
from legal obligations.
Summary of pages
This document comprises a front cover, an inside front cover, pages i and ii,
pages 1 to 10, an inside back cover and a back cover.
This standard has been updated (see copyright date) and may have had
amendments incorporated. This will be indicated in the amendment table on the
inside front cover.
ii
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BS 5617:1985
0 Introduction
A urea-formaldehyde foam system is generated at
the point of injection from a mixture of aqueous
resin solution, aqueous foaming hardener solution
and air. The resin and hardener solutions are
supplied at controlled rates to suitable foam system
generating equipment from pressurized pots or by a
pumping system.
The foam system, which is fluid at the time of
injection into the cavity, sets shortly afterwards by
chemical reaction. This chemical reaction continues
and simultaneously loss of residual water occurs by
absorption by and subsequent evaporation from the
wall to produce the final foam.
Urea-formaldehyde foam systems complying with
this standard have a fine, uniform, cellular
structure which is vapour permeable. The foam is
durable and has sufficient strength to be
self-supporting in the cavity.
Because chemical reactions are taking place during
the foam system injection process, some variation in
foam properties can occur due to differences in in
situ operating conditions. Foam system tests are
carried out on site prior to injection to ensure that
the quality of the system to be injected complies
with this standard. These aspects are detailed in
BS 5618.
The thermal insulation is achieved by the foam
restricting air circulation in the cavity and by
limiting radiation losses without adding
substantially to the conducted heat loss. Its
performance is therefore primarily determined by
the extent to which the cavity is filled rather than by
variations in the foam density.
1 Scope
This British Standard specifies the property
requirements, the properties of the components and
the production parameters, of urea-formaldehyde
foam systems suitable for injection into external
masonry or concrete cavity walls to provide
improved thermal insulation.
NOTE The titles of the publications referred to in this standard
are listed on the inside back cover.
2 Definitions
For the purposes of this British Standard the
following definitions apply:
2.1
urea-formaldehyde (UF) foam
an infusible cellular matrix of cured
urea-formaldehyde resin insoluble in water and
other common solvents
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2.2
urea-formaldehyde (UF) foam system
a mixture of urea-formaldehyde resin, hardener,
surfactant, water, air and water additives
2.3
foaming hardener
a mixture of surface active agents and acids that
enables a foam system to be produced by the
introduction of air into an aqueous solution and will
cause UF resin, when mixed into the foam system,
to set to an insoluble, infusible matrix
2.4
cavity
an air space between two leaves of an external wall
2.5
effective density (ED)
the mass of a specified sample divided by its initial
volume using the method described in Appendix A
2.6
declaration
the document supplied by the foam system supplier
to the purchaser or to any authorized testing or
approvals organization, containing relevant details
for the proper use of the foam system
3 Property requirements
NOTE The quality of the foam system depends on the choice of
components (see 4.1) and their method of application as declared
by the foam system supplier (see 4.2).
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BS 5617:1985
4 Processing requirements
Requirement
8
2
0.035
No attack
Class P
Extent of burning not
to exceed 125 mm
Test method
Appendix B
Appendix C
Method 7 of BS 4370-2:1973
Method 3 of BS 1982:1968
BS 476-5
BS 4735
NOTE 1 Because UF foam chars on contact with flame and emits little smoke, the presence of foam tends to reduce the risk of fire
and smoke spread via the cavity. However, the use of UF cavity insulation does not affect requirements for the provision of cavity
barriers.
NOTE 2 For design purposes an effective thermal conductivity value for UF foam installed in masonry cavity walls should be taken
to be 0.04 W/(mK). This aspect is more fully discussed in Appendix J of BS 5618:1985.
a CAUTION. The small scale laboratory test described in BS 4735:1974 is solely for assistance in monitoring
consistency of production and is not for use as a means of assessing the potential fire hazard of a material in use.
Foam stability
Appearance
Permissible
deviations
Test method
25 %
20 %
Appendix A
Appendix B
Appendix D
Appendix E
Appendix F
Appendix G
Table 3 Limiting values and permissible deviations for foam system components
Property
UF resin:
Solid resin yield, % m/m
Density, g/mL
Viscosity, mPas
Free formaldehyde content, % m/m
Water tolerance, % V/V
2
1.5 %
30 %
Between 0 and 1
100
Foaming hardener:
Total acidity, % m/m
2
Surfactant concentration, % KOH m/m 10
Test method
Appendix H
Use a hydrometer complying with BS 718
Method 1 of BS 5350-B8:1977
Appendix J
Appendix K
Appendix L
To be specified by system supplier
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BS 5617:1985
4.2 Declaration
The foam system supplier shall make a declaration
for each foam system with respect to the following
parameters.
a) The dilution at which the UF resin is to be used
and the dilution procedure.
b) The dilution at which the foaming hardener is
to be used and the dilution procedure.
c) The ratio to be used of the diluted UF resin to
the diluted foaming hardener.
d) Any water hardness limitations and the
method of correction.
e) The method of coping with variations in
operating temperatures.
f) The data required in Table 2, the values of the
properties given in Table 3 and the usable limits
as required in Table 4.
Maximum viscosity, s
Minimum water tolerance, % V/V
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Usable limits
Test method
Appendix M
Appendix K
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BS 5617:1985
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C.6 Report
This shall state the water absorption as the average
of the values obtained for the two test pieces and the
date of the test.
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BS 5617:1985
H.1 Principle
The percentage loss in mass of the resin is
determined after the resin has been heated under
specified conditions.
H.2 Test sample
The test sample shall be approximately 3 g of resin.
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H.3 Apparatus
H.3.1 Ventilated oven, capable of being maintained
at a temperature of 120 2 C throughout the
working space.
H.3.2 Flat bottomed dish, 70 mm to 90 mm in
diameter and maximum depth of 100 mm.
H.3.3 Desiccator, containing silica gel.
H.3.4 Balance, capable of determining the mass to
the nearest 0.001 g.
H.4 Procedure
Dry the dish for at least 30 min in the oven at a
temperature of 120 C. Cool in the desiccator and
weigh to the nearest milligram.
Put into the dish 2 0.2 g of resin, spreading the
contents as evenly as possible over the bottom of the
dish. Record the mass of the dish and contents to the
nearest 0.001 g.
Place the dish and contents in the oven on a level
perforated sheet metal shelf and maintain at a
temperature of 120 2 C for a period of 3 h.
Remove the dish and contents from the oven and
allow to cool in the desiccator. Remove the dish and
contents from the desiccator and redetermine the
mass immediately.
H.5 Calculation and expression of results
Calculate the percentage solid resin yield SRY (in %
solids m/m) from the equation:
( M 3 M 1)
SRY = ----------------------------- 100
( M 2 M 1)
where
M1 is the mass of the dish;
M2 is the mass of the dish and contents before
heating:
M3 is the mass of the dish and contents after
heating.
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BS 5617:1985
J.2 Reagents
J.2.1 Hydrated sodium sulphite 20 % (m/m)
solution.
J.2.2 Thymolphthalein indicator 1 % (m/m)
in 50 : 50 V/V 64 O.P. industrial methylated spirits:
distilled water solution.
J.2.3 Sulphuric acid. c (H2SO4) = 0.5 mol/L.
J.2.4 Sulphuric acid. c (H2SO4) = 0.05 mol/L.
J.2.5 Sodium hydroxide. c (NaOH) = 0.1 mol/L.
J.3 Apparatus
J.3.1 Conical flask, 100 mL capacity, stoppered.
J.3.2 Weighing bottle
J.3.3 Ice bath
J.3.4 Burette
J.3.5 Balance, capable of determining the mass to
the nearest 0.01 g.
J.4 Procedure
From the weighing bottle weigh accurately 6 0.1 g
of the resin into the stoppered conical flask.
Add 15 mL of deionized water and three to four
drops of the thymolphthalein solution. Shake the
mixture vigorously until the complete solution of the
resin is obtained. Neutralize the solution with 0.1
mol/L sodium hydroxide or 0.05 mol/L sulphuric
acid as required. Cool the solution to + 0.5 C.
Add 25 mL of the sodium sulphite solution,
previously cooled to a temperature of 0.5 C. If free
formaldehyde is present, a brilliant blue colour
appears. Run in rapidly from the burette the 0.5
mol/L sulphuric acid until the colour disappears.
Check the end point by adding one or two extra
drops of the indicator solution and note if this
addition causes any colouration. When no further
colouration is observed the end point has been
reached.
J.5 Calculation and expression of results
Calculate the percentage of free formaldehyde
content F (in %m/m), from the equation:
3S
F = ------M
where
S is the volume of 0.5 mol/L sulphuric acid
used (in mL);
M is the mass of the test portion (in g).
K.1 Principle
Water tolerance is determined by progressively
diluting the resin solution to determine the dilution
at which precipitation of the resin occurs.
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Tolerance
mL
% V/V
0
2
4
6
8
10
12
14
16
18
20
22
24
100
140
180
220
260
300
340
380
420
460
500
540
580
K.6 Report
Report the percentage water tolerance WT.
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M.3 Apparatus
M.3.1 No. 6 flow cup, complying with BS 3900-A6.
M.3.2 Cup stand
M.3.3 Orifice plug for each cup.
M.3.4 Stop watch
M.3.5 Beaker, of capacity 100 mL.
M.3.6 Water bath, capable of being maintained
at 25 0.5 C.
M.3.7 Thermometer
M.4 Procedure
Immerse the resin sample, enclosed in a
screw-topped bottle, and the test cup in the water
bath for 2 h or until the resin sample has reached a
temperature of 25 0.5 C. Dry the cup, plug it,
clamp it into the stand, and place the beaker
beneath the cup. Pour the resin sample into the cup
until it runs into the overflow.
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BS 5617:1985
Publications referred to
BS 476, Fire tests on building materials and structures.
BS 476-5, Method of test for ignitability.
BS 718, Specification for density hydrometers.
BS 1982, Methods of test for fungal resistance of manufactured building materials made of or containing
materials of organic origin.
BS 3900, Methods of test for paints.
BS 3900-A6, Determination of flow time by use of flow cups.
BS 4370, Methods of test for rigid cellular materials.
BS 4370-2, Methods 610.
BS 4735, Laboratory methods of test for assessment of the horizontal burning characteristics of specimens
no larger than 150 mm 50 mm 13 mm (nominal) or cellular plastics and cellular rubber materials when
subjected to a small flame.
BS 5350, Methods of test for adhesives.
BS 5350-B8, Determination of viscosity.
BS 5618, Code of practice for thermal insulation of cavity walls (with masonry or concrete inner and outer
leaves) by filling with urea-formaldehyde (UF) foam systems.
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