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Kcse 2023 Chemistry Replica.
Kcse 2023 Chemistry Replica.
CHEMISTRY
(KCSE PREDICTIONS 1-10)
CONFIDENTIAL!
CHEMISTRY
PAPER 1 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
1) Write your NAME and INDEX NUMBER in the space provided above
2) Sign and write the date of examination in the spaces provided above
3) Answer ALL the questions in the spaces provided
4) ALL working must be clearly shown where necessary.
5) Mathematical tables and silent electronic calculators may be used.
Total
80
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
Glass rod
Concentrated Ammonia
Solution
a) Name B (1mark)
b) What is the purpose of the thermometer (1mark)
c) Which liquid was collected in the test tube? 1mark
8. Draw a dot (.) and cross (x) diagram to show bonding in carbon (II) oxide. (2mrks)
9. Ammonium nitrate was gently heated and the products collected as shown in the diagram.
a) Identify:
i. Colourless liquid H (1mark)
ii. Gas G (1mark)
b) Describe one physical and one chemical test that can be used to identify gas G. (2mrks)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
10. Air was passed through several reagents as shown in the flow chart below.
Escaping gases
12. The diagram below shows the acidic and basic oxides fit into the general family of oxides.
Acidic Basic
Oxide Oxide
a) State the name given to the type of oxide that would be placed in the shaded area.(1mark)
b) Give the name of any oxide that would be placed in the shaded area. (1mark)
Unburnt part
Charred black
CHEMISTRY
PAPER 2 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
1) Write your name and index number in the spaces provided above.
2) Sign and write the date of exam in the spaces provided above.
3) Answer ALL the questions in the spaces provided.
4) Mathematical tables and silent electronic calculators may be used.
5) All working MUST be clearly shown where necessary.
1-7
Total score 80
A
I B C D E
F G H
a) Name one condition that is missing in the set up that must be present if the experiment to proceed.
1mark
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
b) If the experiment was carried out properly. What observation would be made in the combustion
tube? 1mark
c) Give an equation for the reaction that occurs in the combustion tube. 1 ½ mark
d) Give an equation for the reaction that takes place as gas x burns. 1 ½ marks
e) Why is it necessary to burn gas x? 1mk
f) Name the reducing and oxidizing agent. 2marks
(i) Reducing agent
(ii) Oxidising agent
g) Identify any other substance that would have the same effect on copper (II) oxide as carbon (II)
oxide. 1mark
h) What would happen if copper (II) oxide was replaced with sodium oxide? Explain 2mark
3. a) Sulphur occurs naturally in two different forms called allotropes;
(i) What are allotropes? 1mark
(ii) The two allotropes of sulphur are stable at different temperatures, as shown in the equation below.
Above 95.50C
Rhombic sulphur Monoclinic sulphur
Below 95.50C
Give a name to the temperature 95.50C 1mark
b) Below is a flow chart diagram for the contact process for the manufacture of sulphuric (VI) acid.
Ammonia
Step IV
H2(g)
Brown Solid L
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(i) List the raw materials used in the manufacturer of ammonia gas. 1mark
(ii) What catalyst is used in step I? 1mark
(iii) Write an equation for the reaction that occurs between ammonia and oxygen gas in the
presence of a catalyst. 1mark
(iv) Identify the process is step II? 1mark
(v) Using an appropriate equation, explain how the reaction in step III occurs (1 mark)
(vi) What should be added to solution K to form solid L? (1 mark)
(b) I. Write the formula of compound J.
II. Calculate the mass of compound J that would contain 14g of nitrogen. (N=14, O=16, H= 1)
(2marks)
b) Explain the advantage of using ammonium phosphate fertilizer over the other nitrogenous
fertilizers. (1mark)
Air
A B M
Substance T
Dry air
Sodium Compressor
Carbonate
solution
D
X
Nitrogen boiling
point- 1960C
Fractional
distillation
Argon boiling
point -1860C
R
Oxygen boiling
point - 1960C
(i) State and explain what will happen in the three test-tubes R, S and T after seven days. 3marks
(ii) Give one reason why some metals are electroplated. 1mark
7. Below is a scheme of some reactions of propanol. Study it and answer the questions that follow.
Polymerisation HBr
Q Y Z
Propanol
CH3CH2CH3
CH3CH2CH2OH
Step III
CH3CH2CH2CL
CHEMISTRY
PAPER 1 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS
a) Answer ALL questions in the spaces provided
b) Show your working clearly.
c) Electronic calculators and Mathematical tables may be used.
d) All answers must be written in English language
8. The formulae below represents active ingredients of two cleansing agents A and B
(a) Name the class to which each of the cleansing agent belongs (2mks)
(b) Which one of the cleaning agent above is not environmental friendly? Explain (2mk)
(c) Which one of the cleansing agent would be suitable to be used in water containing magnesium
hydrogen carbonate? Explain (2mks)
(d) During Saponification process, a small amount of Sodium Chloride is added Give a reason
(1mk)
9. (a) Write an equation showing how ammonium nitrate may be prepared starting with ammonia
gas (1mk)
(b) Calculate the maximum mass of ammonium nitrate that can be prepared using 5.3kg of
ammonia (H=1, N=14, O=16) (2mks)
10. Plastics and rubber are extensively used to cover electrical wires.
(a) What Name is used to describe plastic and rubbers used in this way? (1mk)
(b) Explain why plastics and rubbers are used for this purpose (1mk)
11. G grams of a radioactive isotope take 120days to decay to 3.5grams. The half-life period of the
isotope is 20days
(a) Find the initial mass of the isotope (2mks)
(b) Give two applications of radioactivity in medicine (2mks)
(c) Uranium -238 disintegrates by emitting an alpha particle to form substance Y.
Nuclide Y emits a beta particle to form substance Z. Write down nuclear equations to show how
substance Y and Z are formed (U=92) (2mks)
Copper Pyrites
Gas Q Gas Q
Step (V)
FeO Pure
Copper
(a) Name gas Q (1mk)
(b) With the help of diagram, describe how step (V) is carried out (3mks)
(c) During purification of copper by electrolysis, 1.48g of copper were deposited when a
Current was passed through aqueous copper (II) sulphate for 2 ½ hours. Calculate the amount of
current passed (Cu = 63.5 1Faraday = 96500C) (3mks)
(d) What is meant by the term Froth Floatation (2mks)
(e) Name two impurities present in the ore of copper (1mk)
13. State two properties of Duralumin that make it suitable for use in making aircraft parts?(1mk)
14. The flow chart below shows a sequence of chemical reactions starting with Zinc. Study it and
answer the questions that follow:-
Step 2 Step 3
Zn(s) Step 1 Zn2+(aq) Zn(OH)2(s) ZnO(s)
Dilute
hydrochloric acid
Step 4 H2SO4(aq)
Step 5
Zn(s)
Zn2+(aq)
ii) Explain why hydrogen gas is not liberated when dilute nitric acid is used in step 1 (1mk)
iii) a) Write an ionic equation for the reaction that took place in step 1 (1mk)
b) Calculate the volume of 3M hydrochloric acid that was needed to react completely with0.5g of
Zinc powder (Zn = 65.0) (2mks)
15. Briefly describe how a pure sample of lead ii iodide can be prepared in the lab given Distilled
water, solid lead ii nitrate and solid Potassium iodide (3mks)
16. Use equations only to explain how slag is formed in the Blast furnace during the extraction of
iron (2mk)
17. Using dots and crosses to represent electrons draw the structure Phosphorous chloride (PCl3)
(1mk)
19. Study the information in the table below and answer the questions that follow:
(The letters do not represent the actual symbols of the elements)
20. Chlorine has a higher boiling point than Argon. Give a reason (1mk)
21.i) State Graham’s Law of diffusion (1mk)
ii) Gas B takes 110 seconds to diffuse through a porous pot, how long will it take for the
Same amount of ammonia to diffuse under the same conditions of temperature and pressure?
(RMM of B = 34 RMM of ammonia = 17) (2mks)
i. Name a suitable pair of electrode that can be used in the above process. (½ mk)
ii. State and explain the changes on the concentration of magnesium sulphate solution as the process
proceeds. (1mk)
iii. Label on the diagram the Cathode and anode (1mk)
23.i. Bond energies for some bonds are tabulated below:-
BOND BOND ENERGY KJ/mol
H–H 436
C=C 610
C- H 410
C-C 345
Use the bond energies to estimate the enthalpy for the reaction
C2H4(g) + H2(g) C2H6(g) (2mks)
ii. Study the diagram below and answer the questions that follow:
NH4+(g) +Cl-(g)
∆H2
∆H1
Energy
NH4+(g) +Cl-(g)
∆H3
NH4Cl(s)
Reaction Co-ordinate
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
CHEMISTRY
PAPER 2 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
1. Write your name and admission number in the spaces provided above.
2. Sign and write the date of the examination in space provided.
3. Answer ALL the questions in the spaces provided in the question paper.
4. All working MUST be clearly shown where necessary.
5. Mathematical tables and silent electronic calculators may be used.
QUESTION 1
(a) The grid below represents part of the periodic table. Study it and answer the questions that
follow: The letters do not represent the actual symbols of the elements.
A
B
C D E
F
(i) What name is given to the group of elements to which C and F belong? (1mk)
(ii) Explain the difference in reactivity between element C and D (2mks)
(iii) Using( .) and cross (x) illustrate the bond between B and E (2mks)
(iv) Write a balanced chemical equation for a reaction between element D and oxygen gas
(1mk)
(v) On the grid indicate a tick(√) the position of element G which is in the third period of the
periodic table and forms G3- ions (1mk)
(b) Study the information in the table below and answer the questions that follow: (The letters do not
represent the actual symbols of the substance)
Substance Melting point 0C Boiling points 0C Solubility in water Density at room temp in
g/cm3
H -117 78.5 Very Soluble 0.8
J -78 -33 Very Soluble 0.77x10-3
K -23 77 Insoluble 1.6
L -219 -183 Slightly Insoluble 1.33x10-3
(i) Which substance would dissolve in water and could be separated from the solution by fractional
distillation in the school laboratory (1mk)
(ii) Which substance is a liquid at room temperature and when mixed with water two layers would be
formed. (1mk)
QUESTION 2
(a) Propane can be changed into methane as shown below:
2CH3CH2 CH3 (g) high temperature CH4 (g) + C2 H4 (g) + CH3CHCH2 (g) +H2 (g)
(i) Name the process undergone by propane (1mk)
(ii) Write the equation of reaction between ethene and chlorine gas and name the product. (2mks)
(b) The diagram below shows an incomplete set-up of the laboratory preparation and collection of
Ethene gas:
Conc H2SO4
Substance Y
Substance x
WOODEN
BOX
HEAT
(i) Complete the diagram to show how Ethene gas is collected. (2mks)
(ii) Name substances X and Y (2mks)
(iii) Apart from being colourless and odourless, state another physical property of ethene.(1mk)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
(c). the table below gives information about the major components of crude oil. Study it and answer
the questions that follow.
Components Boiling points0C
Gases Below 40
Petrol 40-175
Kerosene 175-250
Diesel oil 250-350
Lubricating oil 350-400
Bitumen Above 400
(i) Which of the compounds of crude oil has molecules with the highest number of atoms? Explain.
(2mks)
(ii) Explain the condition that could cause a poisonous gas to be formed when kerosene is burnt?
(2mks)
QUESTION 3
(a) Air is a mixture of gases that can be classified as active and inactive part. The diagram below
represents an experiment that can be carried out to determine the active part of air.
(a) Describe how this set-up can be used to determine the active part of air (4mks)
(b) When magnesium ribbon is heated in air the mass of the product is more than the mass of
magnesium ribbon used. Explain (1mks)
(c) Carbon (IV) oxide and sulphur (IV) oxide are some of the gases that are common pollutant in the
atmosphere. Explain two measures that are taken to reduce atmospheric pollution of the two
gases. (2mks
Liquid air
-1960C -1860C -1830C
Fractional
distillation
(i) Explain how carbon (IV) oxide and water are removed before liquification of air. (2mks)
(ii) Identify the component that is collected at -1860C (1mk)
(iii) State one commercial use of oxygen gas apart from its use in hospital by patient with
difficult breathing (1mk)
QUESTION 4
(a) Rhombic and Monoclinic are allotropes of sulphur. They are interconvertible as shown below:
960c
Rhombic Monoclinic
(i) What does the temperature 960C represent (1mk)
(ii) State the differences in crystalline appearances between rhombic and monoclinic crystals. (1mk)
(b) The chart below shows some process involved in large scale production of sulphuric (VI) acid.
Use it to answer the question that follows: substance A
sulphur (iv) oxide
Oxygen Reaction SO2 Absorption oleum
chamber chamber oleum
Water
(2)(i) Name substance A (1mk)
(ii).Write an equation that takes place in the absorption chamber (1mk)
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(iii) Vanadium (V) oxide is commonly used as an catalyst in the contact process:
(I) Name another catalyst that can be used in this process. (1mk)
(II) Give two reasons why vanadium V oxide is the commonly used catalyst. (2mks)
(III) State and explain the Observation made when concentrated sulphuric (VI) acid is added to
crystals of copper (II) sulphate in a beaker. (2mks)
(v). If 100kg of sulphur( IV) oxide is used in one day by this plant, determine the mass of oleum
produced in one day. (S=32. O=16 H=1) (3mks)
QUESTION 5
(a) Draw a well labeled diagram of set-up that can be used to prepare dry hydrogen gas in the
laboratory. (3mks)
(b) The experiment below was carried out to investigate the reaction between steam and
magnesium. Use it to answer the questions that follow:
(c)The diagram below shows a sample of hard water being passed through a vertical column to
remove its hardness. Hard water containing MgCl2
Na + Na +
Na + Na +
Ion exchanger
Na +
Na +
Na + Na +
(i) Write the formula of the two cations present in the sample of hard water. (2mks)
(ii) What name is given to the above method of softening hard water. (1 mk)
(iii) Write an ionic equation to show how the hard water is softened. (1 mk)
(iv) Study the table below and answer the questions that follow.
Salt Solubility (g/100g of water) at Solubility (g/100g of water) at
200 C 500 C
P 10 20
Q 15 12
QUESTION 7
(a) A student set out to prepare iron (III) chloride using the apparatus shown in the diagram below:
CHEMISTRY
PAPER 1 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
a) Answer all the questions in the spaces provided.
b) Mathematical table and electronic calculators may be used
c) All workings must be clearly shown where necessary
d) Answer all questions in English.
1-30 80
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
a) Arrange the metals in order of reactivity starting with the most reactive. (2 mks)
b) Which of the carbonate is soluble in water? (1 mk)
2. Samples of urine from three participants E, F and G at a national police recruitment exercise
were spotted onto a chromatography paper alongside two illegal drugs D1 and D2. A
chromatogram was run using ethanol. The diagram below shows the chromatogram.
Solvent Front
Baseline
D1 D2 E F G
6. Study the diagram below and answer the questions that follow.
Ca (OH)2
CaC2 + X
Step 1
Gas Y 1 mole HCl Z
Step 2
H H 1 mole H2
| | Step 3
C — C
| 2000C, High pressure C2H4 H2 1500C CH3CH3
H H 2 Step 5 Step 4
7. Describe a laboratory experiment that can be used to obtain aluminum chloride from a mixture of
sodium chloride and aluminum chloride. (2 mks)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
8. The graph below shows the solubility curves for salts J and K.
11. The empirical formula of a hydrocarbon is C2 H3. It has a molecular mass of 54.
a) Determine the molecular formula of the hydrocarbon. ( C= 12, H= 1) (1 mk)
b) Draw the structural formula and name the hydrocarbon. (2 mks)
12. Write chemical equations to show the difference between the bleaching action by chlorine and
bleaching action by sulphur (IV) Oxide gases. (2 mks)
13. Elements Q and R have atomic numbers 12 and 17 respectively.
a)i) Which element is a metal. (1 mk)
ii) Which dot(.) and (x)cross to represent electrons, show the bonding between Q and R in the
compound of the elements. (2 mks)
a) What is the role of hydrated copper (II) Sulphate in the set- up. (1 mk)
b) Identify Gas S? (1 mk)
c) Write a chemical equation for the reaction taking place in the combustion tube. (1 mk)
15. Calculate the number of aluminum ions in 250 cm3 of 0.1 M aluminum sulphate.
(Avogadro’s Constant = 6.0 x1023) (3 mks)
16. The table below shows solutions and their PH values.
Solution PH Value
T 1.5
U 7.0
V 14.0
a) Select any pair that would react to form a solution of PH 7. (1 mk)
b) Identify two solutions that would react with Alluminium hydroxide.Explain your answer.(2 mk
17. Name two allotropes of carbon. (2 mks)
18. 20 cm3 of gas W takes 12.6 seconds to pass through a orifice. 10cm3 of Oxygen gas takes 11.2
seconds to diffuse through the same orifice under same conditions of temperature and pressure
calculate the molecular mass of gas W. (2 mks)
19.The diagram below shows an incomplete set- up of the laboratory preparation of dry carbon (IV)
Oxide. Complete the diagram. (3 mks)
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22. In one of the dry practicals assignment to analyze cation a salt, the following observations were
made:
Test Observation Inference
(i) NaOH dropwise till in excess White ppt formed soluble in
excess
(ii) NH3 solution dropwise till in Presence of Zn2+ ions
excess. confirmed.
(a) Fill in the blanks in the table above. (2 mks)
(b) Give an ionic equation for the reaction that occurs in test (ii) when excess NH3 solution is added.
(1 mk)
23.Describe how you would prepare a pure sample of lead (II) carbonate starting with lead (II )
oxide. (3 mks)
24.Explain how sodium hydrogen carbonate and ammonium chloride are separated in solvey
process. (2 mks)
25.a) What is fuel? (1 mk)
b) Firewood is the main source of fuel in most Kenyan homes. State two effects of
wood products of burning fuel on environment. (1 mk)
29. The diagram below shows sodium metal being dropped in water. Study it and answer the
questions that follow;
i) State and explain two observations made during the reaction. (2 mks)
ii) Write an equation for the reaction that takes place during the experiment. (1 mk)
30. i) In an experiment to determine solubility of solid P in water at 25 0C, the following results
were obtained.
Mass of empty evaporating dish – 24.2g
Mass of evaporating dish + saturated solution = 40.4g
Mass of evaporating dish + dry solid P = 28.4g
Using the information above calculate the solubility of solid Pat 25 0C in g/100g of water. (2 mks)
ii) State one precaution observed when carrying out the experiment in (i) above (1 mk)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
CHEMISTRY
PAPER 2 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
a) Write your name , Adm No and Class in spaces provided above.
b) Sign and write the date of examination in the spaces provided above
c) Answer all the questions in the spaces provided below each question. .
d) KNEC Mathematical tables and silent electronic calculators may be used.
e) All working must be clearly shown where necessary.
2. (a) When few drops of ammonia solution was added to hydroxides of zinc, copper and
Iron(III), the following solution were obtained; colourless solution, deep blue
solution and brown precipitate. Identify the substances responsible for;
(i) Deep blue solution (1 mk)
(ii) Colourless solution (1 mk)
(iii) Brown precipitate (1 mk)
(b)A saturated solution of potassium chloride is to be prepared at 40 oC. Its solubility at 40oC is
34g/100g water and 27g/100g of water at 5oC .
(i) What mass of water would be saturated with 8.5g of potassium chloride at 40 oC? (1mk)
(ii) What mass of potassium chloride would crystallize out if the saturated solution at
40oC is cooled to 5oC? (1 mk)
(c)Given two samples of sodium carbonate and sodium hydrogen carbonate. Describe a
chemical test that would distinguish them. (2 mks)
(d) Two equal pieces of magnesium ribbon were placed in two separate test tubes, one containing
10cm3 of water and the other containing 10cm3 of methylbenzene. State and explain the
observations made in the two test tubes. (2 mks)
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(e) In an experiment, soap solution was added to three separate samples of water. The table
below shows the volumes of soap solution required to form lather with 2 litres of each
sample of water before and after boiling.
Sample Sample A Sample B Sample C
Volume of soap before water is boiled (cm3) 30 3 13
Volume of soap after water is boiled (cm3) 30 3 3
3. (a) 12.0cm3 of 0.05M hydrochloric acid reacted completely with calcium hydrogen
carbonate solution.
(i) Write the chemical equation for the reaction. (1 mk)
(ii) Calculate the number of moles of hydrochloric acid used. (1 mk)
(iii) Determine the number of moles of calcium hydrogen carbonate used. (1 mk)
(b) Study the flow chart below and answer the questions that follow.
Sulphur
Step I
Step 2 Step 3
Sulphur (IV) oxide Sulphur (VI) oxide Concentrated
sulphuric (VI) acid
Gas K
Zinc metal
(ii) Use the information below to answer the questions that follow.
C(s) + O2(g) CO2(g) H = - 393Kjmol-1
H2(g) + ½ O2 (g) H2O (l) H = -287 Kjmol-1
C3H8 + 5O2(g) 3CO2(g) + 4 H2O(l) H = -2209kj mol-1
I. What does the symbol H represent? (1 mk)
II. Write the equation for the formation of propane from its constituent elements. (1 mk)
III. With the aid of an energy cycle diagram, calculate the enthalpy of formation of propane.
(3 mks)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
5. The flow chart below shows an analysis of mixture K that contains two salts. Study it and
answer the questions that follow.
White precipitate
that dissolves
(a) Identify,
(i) Solution L: (1 mk)
(ii) Solid M: (1 mk)
(iii) Solution N : (1 mk)
(b) What condition is necessary in step 1 (1 mk)
(c) State the observations made in step 1 (1 mk)
(d) Write down an equation to show how;
(i) Solution N is formed. (1 mk)
(ii) Colourless solution A and Ammonia gas are formed. (1 mk)
(e) When excess NaOH(aq) is added to solution N, a white precipitate is formed which dissolves.
Give the name and formula of the ion formed. (2 mks)
Name:……………………………………………………………………………………………….
Formula: …………………………………………………………………………………………….
(f) Explain why it is necessary to add water to mixture K and then filter. (1 mk)
Water
7. A piece of marble chip (calcium carbonate) is put in a beaker containing excess of dilute
hydrochloric acid which is placed on a reading balance. The mass of the beaker and its contents
is recorded every two minutes as shown in the table.
Time (min) 0 2 4 6 8 10 12
Mass (g) 126.4 126.3 126.2 126.1 126.0 126.0 126.0
Progress of reaction
CHEMISTRY
PAPER 1 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
• Write your name and Index number in the spaces provided above.
•Sign and write the date of examination in the spaces provided above.
• Answer all the questions in the spaces provided
•Mathematics tables and electronic calculators may be used.
•All working must be clearly shown where necessary.
The first gas which evolved turned moist red litmus paper to blue. Later the other gas involved
turned the litmus back to red.
(a) Identify solid B (1mk)
(b) Write the equation for the reaction that take place in the test tube (1mk)
7. The apparatus shown below was used to investigate the effect of Carbon (II) Oxide on Lead (II)
Oxide.
(a) State the observation made in the combustion tube during the experiment. (2mks)
(b) Write the equation for the reaction that take place in test-tube E. (1mk)
8. (a) Lime water is also used to soften hard water. Why is this method not preferred to soften
hard water. (1mk)
(b) Name a compound that causes temporary hardness of water. (1mk)
(c) State one disadvantage of using hard water for domestic purpose. (1mk)
9. (a) Name the compound below
CH3CH2CH = CH2
(b) Draw and name other isomers of the compound in (a) above. (2mks)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
10.A white solid dissolve in water to form a colourless solution. The colourless solution forms a
white precipitate with Ammonia solution but dissolve in excess alkali. The colourless solution
forms a white precipitate with Lead (II) Nitrate solution. The white Precipitate dissolve on
warming to form a colourless solution.
(a) Write the chemical formulae for the ion formed when the colourless solution react with excess
ammonia solution. (1mk)
(b) Write the name of the ion present in the white solid. (1mk)
(c) What is an alkali (1mk)
11. The solubility of Potassium Manganate (VII) at 20 0C is 13g per 100g of water and at 900C is 60g
per 100g of water.
(a) Determine the mass of Pottassium (VII) Manganate present in 80g of saturated solution at 900C.
(1mk)
(b) Calculate the mass of Pottassium (VII) Manganate that would crystallize out if the solution
in (a) were cooled to 200C. (2mks)
12. (a) Explain why concentrated Sulphuric (VI) acid is a poor electrolyte and has no effect on
blue litmus paper whereas 2M Sulphuric (VI) acid conducts electricity and changes blue litmus
paper red. (1mk)
(b) What is a binary electrolyte. (1mk)
13. An element F has a relative atomic mass of 88. When a current of 0.5 amperes was persed
through the fused chloride of F for 20 minutes and 20 seconds, 0.278g of F were deposited at the
cathode. Determine the charge on ion of F (1Faraday = 96500C). (2mks)
14. Below is a cross- section of a charcoal burner
CHEMISTRY
PAPER 2 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
• Write your name and Index number in the spaces provided above.
•Sign and write the date of examination in the spaces provided above.
• Answer all the questions in the spaces provided
•Mathematics tables and electronic calculators may be used.
•All working must be clearly shown where necessary.
6. The set-up below was used to prepare and collect gas X. During the experiment cleaned
magnesium ribbon was strongly heated before heating the wet glass wool.
6. The flow chart below shows the large-scale manufacture of nitric (V) acid. Study it and answer
the questions below.
(f) The apparatus below was arranged to investigate the properties of nitric (V) acid. Study the set-
up and answer the questions that follow:
(i) Explain what would be observed when blue and red litmus paper is dropped into flask Y after the
experiment. (2 mrks)
(ii) Write an equation for the reaction in test tube X above. (1 mark)
(iii) What gaseous products would be expected if concentrated sulphuric (VI) acid was used in
place of conc. nitric (V) acid? (1 mrk)
7. (a) Explain the following observation, giving an equation where necessary. When a
sample of tap water is boiled for some time, a white precipitate is formed. (lmk)
(b) A sample of hard water is found to contain 0.25g of calcium chloride and 0.24g of
magnesium sulphate per litre.
(i) Describe how this sample of water is softened by using anhydrous sodium carbonate
(2mks)
(ii) Calculate the mass of anhydrous sodium carbonate required to soften a litre of the water
sample (Ca= 40, Mg = 24, Na = 23, 0 = 16, Cl = 35.5, S = 32 and C = 12) (3mks)
(iii) Give two reasons why it is necessary / important to soften tap water supplied for
domestic . (2mks)
CHEMISTRY
PAPER 1 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
Write your name and admission number in the spaces provided.
Answer all questions in the spaces provided
KNEC mathematical tables and silent electronic calculators may be used for calculations.
All workings must be clearly shown where necessary.
1-29 80
(a) Name one source of hydrogen gas used in this process. (1 mark)
(b) Name the catalyst used in the above reaction. (1mark)
(c) State any two uses of ammonia. (1 mark)
b) The table below gives the rate of decay for a sample of radioactive element K. Study it and
answer the question that follows:
Mass (kg) Time(Days)
72 0
9 120
Determine the half-life of element K. (2 marks)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
4. The pH values of some solutions labeled K,H,L,P and R are given in the table below. Use the
information to answer the questions that follow.
pH 8.0 14.0 1.0 6.5 7.0
Solution K H L P R
(a)Identify the solution with the highest concentration of hydroxyl ions. (1 mark)
(b)Which solution is likely to be sodium chloride solution? (1 mark)
(c)Which solution would react most vigorously with magnesium metal? (1 mark)
5.a) Name the class to which the following cleansing agents belong: (1mark)
b) Which cleaning agent between (i) or (ii) above is preferred for cleaning garments while using
water from a dam containing dissolved calcium chloride? Explain (2 marks)
6. Describe how crystals of sodium chloride can be prepared starting with 50cm3 of 2M sodium
hydroxide solution. (3marks)
7.a) Propane (C3H8) and Carbon(IV)oxide (CO2) diffuses at the same rate under the same conditions.
Explain. (1 mark)
b) Propane is a hydrocarbon. What does the term hydrocarbon mean? (1 mark)
8. The reaction between hydrochloric acid and potassium dichromate (VI) can be used to
demonstrate a reversible reaction. The ionic equation is given below
Explain the observation that would be made when few drops of dilute hydrochloride acid is added to
the equilibrium mixture. (2marks)
a) Draw an energy cycle diagram and label the various heat changes. (2 marks)
b) Use the energy circle above to calculate heat of formation of methanol. (1 mark)
19. The solubility of iron (II) sulphate at 22oC is 15.65g/100g of water. Calculate the mass of iron
(II) sulphate crystals in 90g of saturated iron (II) sulphate solution. (2marks)
Atomic 18 5 3 5 20
number
Mass number 40 10 7 11 40
21. A solid sample was suspected to contain zinc (II) ions. Describe a systematic test to confirm the
presence of zinc (II) ions. (3 Marks)
22.During the electrolysis, a current of 2 amperes was passed through the copper (II)
sulphatesolution for 4 hours. Calculate the volume of the gas produced at the anode. (1 F= 96500
C, MGV = 24000cm3). (3 marks)
23. A volume of 10cm3 of ethene gas (C2H4) was exploded with 50cm3 of oxygen.
(i) Write the equation of the reaction for the combustion of ethene. (1mk)
(ii) Calculate the volume of gaseous mixture. (2marks)
28. Sodium hydroxide can be prepared through the following methods: I and II.
CHEMISTRY
PAPER 2 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS
Write your name and index number in the spaces provided above.
Sign and write the date of examination in the spaces provided above.
Answer all the questions in the spaces provided in the question paper.
Electronic calculators may be used.
All working must be clearly shown where necessary.
WATER LIQUID J
SOLID K
i.Complete the set up to show how dry chlorine may be collected (1 mk)
ii.Name Soild K……………………………………………….. (2 mks)
Liquid J………………………………………………
iii.State and explain the observation made when chlorine gas is bubbled through a solution of
potassium iodide (2 mks)
iv.Write an ionic equation for the reaction that occurs in iii) above (1 mk)
c) Study the flow chart below and answer the questions that follow
Sunlight
Chlorine gas
Solid M
Solution Q
Gas T
Catalyst K Gas R
Water
Gas R
Gas J
OLEUM Liquid S
H2WATER
O
C D E F G
Z
H J
a) i).What chemical family does element J belong to? (1 mk)
ii. Compare the reactivity of element C and H. Explain. (2 mks)
b) i) Write the chemical formula of the chloride of element D (1 mk)
ii) Name the type of structure of the chloride in b(i) above. (1 mk)
c). State and explain the difference in atomic radius and ionic radius of element F (2 mks)
d). Using dots (.) and crosses (x) show how bonding occurs when element E and F react. (1mk)
e). Study the diagram below and answer the questions that follow
TUBE A
ZINC
WET SAND
GAS X
HEAT HEAT
WATER
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
a) Select two half - cells which when combined will give the lowest e.m.f (1mk)
b) Can a solution of silver nitrate be stored in a container of Zinc? (2mks)
c) An iron jug was electroplated using Chromium. The chromium electrode and iron jug were
thoroughly cleaned and weighed before being dipped into the electrolyte. Why was cleaning
necessary? (1mk)
d) A current of 0.75 Amperes was passed through the solution for one hour and four minutes. The
mass of chromium deposited on the jug was 0.52g
(1Faraday = 96500C Cr = 52)
(i) Calculate the quantity of electricity passed. (2mks)
(ii) How many moles in Chromium were deposited? (1mk)
(iii)Calculate the quantity of electricity in coulombs required to deposit one mole of Chromium.
(2mks)
(iv)Deduce the charge of the Chromium ion. (2mks)
5 ) a)An organic compound G whose empirical formula is HCO2 has molar mass of 90. It reacts
with ethanoic in the presence of a few drops of concentrated Sulphuric (VI) acid forming another
compound J with a pleasant smell.
(i) Determine the molecular formula of compound G (2marks)
(ii) To which class of homologous series do compound G and J belong? (2marks)
G: ……………………………………………………………………………………
J: ………………………………………………………………………………………
i. Name process I and name any other product formed in the process.
Process I ½ 𝒎𝒌
Product ½ mk
ii) Name the reagent and condition required in process II.
Reagent ½ 𝒎𝒌
Condition ½ mk
iii) Name the catalyst and reagent required in step IV.
𝟏
Catalyst 𝒎𝒌
𝟐
Reagent ½ mk
iv) Give any one use of the product formed in process (V) (1mk)
v) Name process (VI) (1mk)
6. The flow chart below outlines some of the processes involved in extraction of copper from
copper pyrites. Study it and answer the questions that follow.
CHEMISTRY
PAPER 1 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
1) Write your NAME and INDEX NUMBER in the space provided above
2) Sign and write the date of examination in the spaces providedabove
3) Answer ALL the questions in the spaces provided
4) ALL working must be clearly shown where necessary.
5) Mathematical tables and silent electronic calculators may be used.
1 −28 80
Total 80
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
QUESTIONS
1.In the industrial preparation of oxygen, state:
(a)How dust particles are removed from air. (1 mark)
(b)Why carbon (IV) oxide is removed before the mixture is cooled to – 250C (1 mark)
2. A form four student accidentally mixed Sodium Carbonate and Calcium Carbonate.
Describe how he would obtain a dry sample of Sodium Carbonate from the mixture. (3 marks)
3. The set up below was used to prepare dry hydrogen gas. Study it and answer the questions that
follow.
Hydrochloric
Cardboard
acid
Zinc granules
A gas jar
gas x
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
(a) Identify gas (1 mark)
(b)Write an equation for the reaction that produces gas x. (1 mark)
(c) What is the effect of the gas x above on the red-litums paper (1 mark)
(d) State and explain two observations made when hydrogen sulphide is bubbled through a solution
containing iron (III) chloride. (2mks)
12. Aluminium (III) chloride sublimes. Explain why this is possible. (2mks)
13. The table below shows the solubility of a substance at various temperatures. Study it and answer
the questions that follow.
Temperature (0C) Solubility in g/100g of water
0 36
40 30
80 25
110 20
(a)What is the meaning of solubility? (1 mark)
(b)What is the physical state of the substance? (1 mark)
(c)State and explain what would happen if a sample of a saturated solution of the substance at 400C
was heated to 1100C. (1mark)
14.Study the chart below and answer the questions that follow.
(a) Name:
(i) Cations present in mixture X. (1mark)
(ii) Anions present in the solution. (1mark)
(b) Write an equation to show how the white precipitate in step III is formed. (1mark)
16.The scheme below was used to prepare a cleansing agent. Study it and answer the questions that
follow.
(d) Given to the type of cleansing agent prepared by the method above? (1 mark)
(ii)Name one chemical substance added in step II (1 mark)
(iii)What is the purpose of adding the chemical substance named in c (ii) above? (1 mark)
17. Nitrates of metals A, B, C were heated and the products of the reactions recorded in the table
below.
Nitrate of metal Products
A Metal nitrate and oxygen
B Free metal, nitrogen (IV) Oxide and oxygen gas
C Metal oxide, nitrogen (IV) oxide and oxygen gas
a) Name two possible identities of metal A. (1mk)
b) Name the two possible identity of metal B (1mk)
c) Calcium nitrate is one of the nitrate which forms the products in C. Using chemical equation
show how the products are formed. (1mk)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
18. State and explain what happens to the masses of the following substances when they are
separately heated in open crucibles ; (3mks)
(i)copper metal
(ii) Sulphur powder
19.The table below gives the first ionization energies of the alkali metals.
Element 1st ionization energy kJ mol-1
A 494
B 418
C 519
i) Name the gas that is produced when concentrated sulphuric (VI) acid reacts with the
Sodium chloride (1mark)
ii)Why is it necessary to use a funnel in the beaker? (1mark)
iii)How does the gas affect the PH of the water in the beaker? (1mark)
Dilute
NH3(g) Salt F
H2SO4
Air
Salt V Gas U
Air
Nitric (V) acid Gas W
E
i) Identify U and W
U ……………………………………………………………. (1/2mark)
W …………………………………………………………… (1/2mark)
ii) Give the names of salt F and V
F ……………………………………………………………. (1/2mark)
V ……………………………………………………………. (1/2mark)
iii) Write a balanced equation for the formation of salt F (1 mark)
22.(a)Draw a dot (•) and a cross (x) diagram to show bonding in Cl2O. (1 mark)
b) Explain why the compound Cl2O has a very low melting and boiling point. (1 mark)
23.Ethene reacts with oxygen according to the equation.
C2H4(g) + 3O2(g) 2 C02(g) + 2H2O (g)
15.0 cm3 of ethene were mixed with 50cm3 of oxygen and mixture was sparked to complete the
reaction. If all the volumes were measured at a pressure of one atmosphere and 250C. Calculate
the volume of resulting gaseous mixture. (3 marks)
24. The graph below shows the behavior of a fixed mass of a gas at constant temperature.
Pressure
(atmospheres)
Volume (litres)
(a) What is the relationship between the volume and the pressure of the gas? (1 mark)
(b) 3 litres of oxygen gas at 1atm atmosphere pressure were compressed to 2atm at constant
temperature. Calculate the volume occupied by the oxygen gas. (2mrks)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
26.A student set-up the experiment below to collect gas K. The glass wool was heated before heating
the zinc powder.
Glass wool
Heat Heat
(a) Why was it necessary to heat the moist glass wool before heating the zinc powder? (1 mark)
(b)What observation was made in the boiling tube. (1 mark)
27. During the extraction of lead from its ores one of the main ore used is Galena
CHEMISTRY
PAPER 2 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
Write your name and index number in the spaces provided.
Answer ALL the questions in the spaces provided.
Electronic calculators and Mathematical tables may be used.
All workings must be clearly shown where necessary.
Super heated
water at 170°C
i) Identify (1mark)
X………………………………………………………………………………….................
ii) Why is it necessary to use superheated water and hot compressed air in this process (2mrk)
iii) State two physical properties of sulphur that makes it possible for it to be extracted by this
method (2marks)
b) The diagram below shows part of the process in the manufacture of sulphuric (VI) acid. Study it
and answer questions that follow
Concentrated Sulphuric (VI) acid
Air
Sulphur (IV) Chamber
oxide Purifier A
Sulphur (IV) oxide
+ air
ABSORPTION
TOWER
Oleum
2. Use the standard electrode potential for elements G,H,J, K and L given below to answer the
questions that follow
Half reactions Electrode potential (volts)
G2+(aq) + 2e– G(s) -2.90
H2+(aq) + 2e– H(s) -2.38
J+(aq) + e– ½J2(g) 0.00
K2+(aq) + 2e– K(s) +0.34
½L2(g) + e– L–(aq) +2.87
3. Study the reactive scheme below and answer the questions that follow.
liquid X + Gas Z
O2
Step III
Step I CH3COOH
hydrogen + Q Butanol Substance P
step II
Step IV
H2
CH3CH2CHCH2 Step V
R
H2SO 4 / H2O
Step VI
C4H9OH
Step VII
Electrode Y
molten
alluminium
5. The grid below represents part of the periodic table. Study it and answer the questions that
follow. The letters do not represent the actual symbols of the elements
C F G I
H K
D E
J
Substance M N O P Q R
M.P. °C 801 1356 -101 26 -39 113
B.P °C 1410 2850 -36 154 457 445
Electrical conductivity in solid state Poor Poor Poor Poor Good Poor
Electrical conductivity in molten state Good Poor Poor Poor Good Poor
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
i) Explain why substance M is a good conductor in molten state and not in solid state. (2marks)
ii) What is the most likely structure of substance N. Explain. (2 marks)
iii) Identify, with reasons, a substance that exists as a liquid at room temperature. (2 marks)
6. A piece of marble chip (calcium carbonate) is put in a beaker containing excess of dilute
hydrochloric acid which is placed on a reading balance. The mass of the beaker and its contents
is recorded every two minutes as shown in the table.
Time (min) 0 2 4 6 8 10 12
Mass (g) 126.4 126.3 126.2 126.1 126.0 126.0 126.0
Progress of reaction
CHEMISTRY
PAPER 1 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES:
(i) Write your name and index number in the spaces provided above.
(ii) Sign and write the date of examination in the spaces provided above.
(iii) Answer ALL the questions in the spaces provided.
(iv) Mathematical tables and silent electronic calculators may be used.
(v) All working must be clearly shown where necessary.
(vi) Candidates should check the question paper to ascertain that all the pages
are printed as indicated and that no questions are missing
1 –30 80
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
1. The samples of equal volumes of water were put in 100cm3 conical flasks and heated for 5 minutes
on a Bunsen flame. It was observed that sample 1 registered a low temperature than sample II
Flame 1 Flame II
X
Hot water
. Lie big condenser
Cold
water
Liquid
Distillate
mixture
P
Heat
(a)Name X (1mk)
(b) What is the name given to the method used in separation of mixture P (½mk)
(c) What would happen if the inlet and outlet of water were interchanged ( ½mk)
(d) Which physical property is used to separate mixture P (1mk)
drop wise
Key
+ + + + + + +
charged nucleus
+ + + + + +
electron
+ + + + + +
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
a) State two observations made in the above experiment when sodium react with water (2 mks)
b) Write a chemical equation for the reaction that takes place (1mk)
21. (a) Explain why permanent hardness in water cannot be removed by boiling (2mks)
(b) Name two methods that can be used to remove permanent hardness from water (1mk)
22. Write an equation to show the effect of heat on the nitrate of: - (2mks)
i) Potassium
(ii) Silver
23. Study the diagram below and use it to answer the questions that follow.
Use the bond energies to estimate the enthalpy for the reaction. (3mks)
26. Study the set up below and answer the questions that flows
State all the observations that would be made when the circuit is completed (3mks)
27. Describe how solid samples of salts can be obtained from a mixture of lead (II) chloride, sodium
chloride and ammonium chloride. (3mks)
28. The diagram below represents a set-up used to prepare oxygen gas.
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
29. Two reagents that can be used to prepare chlorine gas are potassium manganate
(VII) and hydrochloric acid.
(a) Write an equation for the reaction. (1mk)
b) Give the formula of another reagent that can be used instead of potassium manganate (VII).
(1mk)
(c) Using an equation illustrate how chlorine bleach coloured substances. (2mks)
CHEMISTRY
PAPER 2 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
1. (a) Study the flow chart below and answer the questions that follow.
CH2 = CH2 C
Step V
Polymerize
B CO2(g) +
H2O(l)
(vi) Give the reagent and the condition necessary for step VI. (2marks)
Reagent:………………………………………………………………………………………………
Condition:………………………………………………………………………………………………
(b) Give the systematic names of the following compounds:
I. CH2CHCHCH2CH3 (1mark)
II. CH C CH3 (1mark)
3. a) Study the table below and answer the questions that follow
Bond type bond energy kJmol-1
C-C 346
C=C 610
C-H 413
C-Br 280
Br-Br 193
i) Calculate the enthalpy change for the following reaction (3 marks)
C2H4(g) + Br2(g) C2H4Br2(g)
ii) Name the type of reaction that took place in (a) above (1mark)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
b) Butane C4H10 cannot be prepared directly from its elements but its standard heat of formation
(∆𝐻ʄ𝜃 ) can be obtained indirectly.
The following heats of combustion are given.
∆𝐻𝐶𝜃 (Carbon) = -393kJ/mol
∆𝐻𝐶𝜃 (Hydrogen) = -286kJ/mol
∆𝐻𝐶𝜃 (Butane) =-2877kJ/mol
i) Draw an energy cycle diagram linking the heat of formation of butane with its heat of
combustion and the heat of combustion of its constituents elements. (1mark)
ii) Calculate the heat of formation of butane ∆𝐻ʄ𝜃 (C4H10) (2marks)
c) Given that the lattice enthalpy of potassium chloride is +690kJ/mol and hydration enthalpies of
K+ and Cl- are -322kJ and -364kJ respectively. Calculate the enthalpy of solution of potassium
chloride. (3 marks)
4. (a) Name two apparatuses that can be used for determining accurate volume in a
laboratory (2marks)
(b) One of the flames produced by Bunsen burner is the luminous flame
i) Explain why this flame is very bright (1mark )
ii) State two disadvantages of the luminous flame (2marks)
(c) Air is usually one of the substances that is considered as a mixture
(i) Identify the two most abundant component of air (2marks)
(ii) Give two reasons why the air is considered as a mixture (2marks)
(iii) One of the components of air is carbon (iv) oxide. Describe an experiment that can be used
to prove the presence of carbon (iv) oxide in the air (2marks)
5. The grid below forms part of the periodic table. Study it and answer the questions that follow.
The letters do not represent the actual symbols of the elements
P T V W Y M
Q S U X
R Z
6. The chart below represents the main steps in the large-scale manufacture of sodium carbonate.
A
Chamber X Ammoniated brine Solvay
Tower
A
CaCl2
Heat Chamber Y
Solution C
B
CO2
Limestone Kiln
Sodium
carbonate
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
(a) (i) Complete the table below giving the names of substance K and L if the gases generated are
carbon (IV) oxide and carbon (II) oxide. (2marks)
Substance Carbon (IV) oxide Carbon (II) oxide
K
L
(ii) Complete the diagram to show how a sample of carbon (II) oxide can be collected. (2marks)
State and explain the difference in observation made in set up I and II above.(3 marks)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
CHEMISTRY
PAPER 1 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
(a). Write your name class and class number in the spaces provided above
(b) Sign and write the date of the examination in the spaces provided above
(c) Answer ALL questions in the spaces provided.
(d) Mathematical tables and electronic calculators may be used.
(e) All working must be shown clearly where necessary.
1 – 27 80
(1mark) (1mark)
3 (a) In an experiment, sulphur was heated in a deflagrating spoon until it begins to burn then
lowered into a gas jar. Explain the observations made. (2 marks)
(b) Explain the role of oxygen in steel making. (2 marks)
4 (a) State Graham’s law of diffusion. (1mark)
(b) At what temperature, in K, assuming constant pressure, is the volume of a fixed mass of gas at
127oC doubled? (2 marks)
5 (a) Distinguish between a temporary physical change and temporary chemical change.(2 marks)
(b) In an experiment, the following substances were heated in separate test tubes. Complete the
table to state the observations and classifying the type of change that occurs. (3 marks)
Solid Observations on heating Type of change
CuSO4.5H2O
KMnO4
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
6. Explain how you would distinguish between ethane and ethyne. (2 marks)
7. Explain how solid calcium sulphate can be prepared from solid samples of calcium carbonate and
sodium sulphate. All other reagents and apparatus are provided. (3 marks)
8 (a)A metal reacts with dilute hydrochloric acid to produce a gas. Explain how to identify the gas.
(1mark)
(b) The diagram below shows the set up used for the reaction between magnesium and steam.
To which groups of the Periodic Table do these three elements, X, Y and Z, belong? (1½ marks)
10. In an experiment silicon (IV) chloride is dissolved in water in a boiling tube.
(a) Write an equation for the reaction that occurs. (1mark)
(b) Explain the observations that were made during the experiment. (3 marks)
14 (a) Write the equation for the reaction between chlorine and cold dilute sodium hydroxide.
(1mark)
(b) When chlorine gas reacts with hot concentrated calcium hydroxide, one of the products formed
is calcium hypochlorite (CaOCl2). This commonly referred to as bleaching powder.
Explain the bleaching action of calcium hypochlorite. (2 marks)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
15. The diagram below shows an apparatus for the laboratory preparation of carbon (II) oxide.
(a) Name:
(i) Catalyst D
(ii) Reaction II
(iii) Reaction III
(iv) Compound Z (4 marks)
(b) State the observations made in step II. (1mark)
(c) Write an equation for the reaction that occurs in step III. (1mark)
19. A student performs two reactions.
reaction 1: 10 g of magnesium ribbon with excess 2.0 mol / dm3 dilute hydrochloric acid
reaction 2: 5 g of magnesium powder with excess 2.0 mol / dm3 dilute hydrochloric acid
In both experiments, the volume of hydrogen produced, V, is measured against time, t, and the
results plotted graphically.
(a) On the grid below, sketch a graph that would be obtained is volume of hydrogen produced is
plotted against time for both reactions1 and 2. (2 marks)
25. The diagram shows the apparatus used to electrolyse lead (II) bromide using inert electrodes.
Why does the lamp light up only when the lead (II) bromide is melted? (2 marks)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
CHEMISTRY
PAPER 2 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
(a) Write your name and class number in each of the foolscaps answer sheets.
(b) Sign and write the date of examination in each of the foolscap answer sheets.
(c) Answer all the questions in this paper on one side of each foolscap.
(b) Study the flow chart below and answer the questions that follow.
3. Next to each letter, A to F, in the table below is the molecular formula of an organic compound.
(a) Choose a molecular formula above that represents an organic compound below. Write down
only the letter (A to F) next to the question numbers
(i) A haloalkane (½ mark)
(ii) An alcohol (½ mark)
(iii) An unsaturated hydrocarbon (½ mark)
(iv) A product of thermal cracking of compound C. (½ mark)
(b) If compound F is a carboxylic acid, write down the following:
(i) The structural formula of a functional isomer (an isomer with a different functional group) of F.
(1mark)
4. The flow chart below summarizes the extraction of Zinc, study it and answer the questions that
follow.
(b) A student has found that her sample of potassium nitrate is contaminated with small amounts of
a green solid. She picks out a small piece of the green solid and finds that it is insoluble in water.
(i)Describe how you would make a pure sample of potassium nitrate from the impure mixture.
(3marks)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
(ii) The student believes that the green solid is copper (II) carbonate. Describe a series of 3 tests that
the student could use to confirm this. (6 marks)
Test Procedure Observations Conclusion
1
(c) In an experiment 50g of a saturated solution of a salt X was heated to dryness in an evaporating
dish. The mass of crystals when weighed gave a reading of 2.7g. Determine the solubility of the
salt. (2 marks)
CHEMISTRY
PAPER 1 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
Write your name and index number in the spaces provided above.
Sign and write the date of examination in the spaces provided above.
Answer ALL the questions in the spaces provided.
Mathematical tables and electronic calculators may be used.
All working MUST be clearly shown where necessary.
1 – 31 80
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
I II III
Gas
collected
a) Identify
i) Gas A (1mk)
ii) White precipitate. (1mk)
b) Write an ionic equation for the formation of white precipitate. (1mk)
A
B
C
Sulphur
deposit
a) Name;
A ( ½mk)
B ( ½mk)
C ( ½mk)
b) Why is C pumped to the Sulphur deposit. ( ½ mk)
c) Which property of sulphur enables it to be extracted by the method above. (1mk)
12. An element A has two isotopes 50A and 52A. The relative atomic mass of A is 51.5
i) Determine the percentage abundance of each isotope. (2mks)
ii) Define the term isotopy (1mk)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
13. Study the table below and answer the questions that follow. The letters are not the actual
chemical symbols of the elements.
Element Atomic number Atomic mass
W 20 40
X 9 19
Y 10 20
Z 17 35.5
i) Identify elements that belong to the same group and give a reason. (2mks)
ii) Which element is a metal. (1mk)
14. Study the information given in the table below and answer the questions that follow
Bond C-H Cl - Cl C - Cl H - Cl
Average bond enthalpy (KJmol-1) 414 244 326 431
Breaking of bond)
a) Calculate the enthalpy change for the reaction (3mks)
CH4(g) + Cl2(g) uv light CH3Cl(g) + HCl(g)
b) Is the reaction exothermic or endothermic?
Explain your answer. (1mk)
15. Study the flow chart below and answer the questions that follow
Step 3
Step 1
16. Soap solution was added to the three samples of water and the amount of soap required to form
lather with 1 litre of each sample of water before and after boiling was recorded as shown below.
I II III
Volume of soap before water is boiled 30 5 12
a) Explain the change in the volume of soap solution used in experiment III. (1mk)
b) Why was the volume of soap used in experiment II so low. (1mk)
17. a) State Avogadro’s law (1mk)
b) 100cm3 of hydrogen was mixed with 300cm3 of chlorine and the mixture allowed to react.
Determine the maximum volume of hydrogen chloride gas that would form. (2mks)
18. The table below shows the tests that were carried out on solid R and the observations made
Test Observations
i)Solid R was heated. Solid R turned from white to yellow.
ii)Dilute hydrochloric acid was added to Colourless solution was formed.
solid R. A white precipitate was formed which dissolved to
iii)To the colourless solution obtained in form a colourless solution.
test II excess sodium hydroxide solution
was added.
Write the formula of cation in;
a) Solid N (1mk)
b) Colourless solution formed in test III (1mk)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
19. The diagram below is a set up of apparatus used during electrolysis of molten copper(II) iodide
Electrode X
Electrode Y
Copper(II)iodide
Copper(II)iodide
A
B
C
D
CHEMISTRY
PAPER 2 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
1.Write your name and admission number in the spaces provided above.
2. Sign and write the date of the examination in space provided.
3.Answer ALL the questions in the spaces provided in the question paper.
4. All working MUST be clearly shown where necessary.
5. Mathematical tables and silent electronic calculators may be used.
(i) What name is given to the family of elements to which A and C belong? (1 mark )
(ii) Write the chemical formula of the sulphate of element D. (1 mark )
(iii) Which letter represents the most reactive ( 2 marks )
(a) Metal
(b) Non-metal
(iv) Name the bond formed when B and H react. Explain your answer. (2 marks )
(v) Select one element that belong to period 4. ( 1 mark )
(vi) Ionic radius of element E is bigger than the atomic radius. Explain. (2 marks )
(vii) The electron configuration of a divalent anion of element N is 2.8.8. Induce the
Position of element N on the periodic table drawn above. (1 mark )
(viii) The oxide of G has a lower melting point than the oxide of L. Explain. ( 1 mark )
(ix) How do the atomic radii of I and C compare. Explain. ( 2 marks )
(x)Explain the trend in the 1st ionization energies of the elements J, I and L. (1mark )
2 a) Define the following terms
i) Saturated solution (1mk)
ii) Fractional crystallization (1mk)
b) Solubility of salt X and Y were determined at different temperatures as shown in the following
data.
Temperature (ºC) 0 20 40 60 80 100
Solubility of 100g of water X 12 30 75 125 185 250
Y 15 20 35 45 65 80
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
i. On the grid provided, plot a graph of solubility (vertical axis) against temperature. (4mks)
ii. From the graph determine the solubility of each at 50ºC.
X ……………………………………………………….. (1mk)
Y ………………………………………………………… (1mk)
iii. At what temperature was the solubility of both salts equal. (1mk)
b)i. What is permanent hardness of water? (1mk)
3. The flow chart below illustrates two industrial processes. Haber and contact processes each with
air as one of the starting materials and other chemical reactions.
AIR Nitrogen B D
Harber
process
Hydrogen
Oxygen
Water
Contact
process
a) (i) Give the name of the process by which air is separated into oxygen and nitrogen.(1 mk)
(ii) Apart from oxygen and nitrogen gas produced from process a(i) name any other gas
produced in the process above. (1 mk)
b) Name the substances which are represented by the letter. (4 mks)
A…………………………….. B……………………………………..
C …………………………. D………………………………………
c) Name the catalyst used in;
(i) The Haber process (1 mk)
(ii) The contact process (1 mk)
(iii) Explain the role of the catalyst in both the Haber and contact process. (2 mks)
d) (i) Write a balanced equation for formation of compound D. (1 mk)
(ii) Calculate the percentage by mass of nitrogen present in compound D
(N = 14.0, H = 1.0, S = 32.0, O = 16.0) (2 mks)
(iii) Give one use of compound D. (1 mk)
(a) Identify two errors from the section of the arrangement shown above (2mks)
I: …………………………………………………………………………………………………
II:……………………………………………………………………………………………………
(b) Complete the diagram to show how dry hydrogen gas can be collected. (2mks)
(c) (i) Explain why hydrogen was collected by the method shown above (1mk)
(ii)Write a balanced chemical equation for the reaction that takes place when hydrogen gas is burnt
in air. (1mk)
(e) Determine the relative atomic mass of zinc, given that when 6.54g of zinc was used, 2.4litres of
hydrogen gas was produced. (Molar gas volume = 24 litres) (3mks)
(c) State any two non-industrial uses of hydrogen gas (2mks)
5. The diagram below shows an experiment set-up to investigate a property of carbon (ii) oxide. Study
it and answer the questions that follow.
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
a) Name one condition that is missing in the set up that must be present if the experiment to proceed.
1mark
b) If the experiment was carried out properly. What observation would be made in the combustion
tube? 1mark
c) Give an equation for the reaction that occurs in the combustion tube. 1 mark
d) Give an equation for the reaction that takes place as gas x burns. 1 marks
e) Why is it necessary to burn gas x? 1mk
f) Name the reducing and oxidizing agent. 2marks
(i) Reducing agent
(ii) Oxidising agent
g) Identify any other substance that would have the same effect on copper (ii) oxide as carbon (ii)
oxide. 1mark
h) What would happen if copper (ii) oxide was replaced with sodium oxide? Explain 2mark
6. Dry chlorine was collected using the set up below.
Air
A B M Substance T
Dry air
X
Nitrogen boiling
D
point- 1960C
Fractional
Argon boiling distillation
point -1860C
R
Oxygen boiling
point - 1960C
f) An investigation was carried out using the set-up below. Study it and answer the questions that
follow.
R T
S
Air Air
Air
Nail
Oil
Water
Anhydrous
Nail calcium Boiled water
chloride Nail
(i) State and explain what will happen in the three test-tubes R, S and T after seven days. 2marks
(ii) Give one reason why some metals are electroplated. 1mark
CHEMISTRY
PAPER 1 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
(a) Write your name and index number in the spaces provided above.
(b) Sign and write the date of examination in the spaces provided above.
(c) Answer ALL the questions in the spaces provided in the question paper.
(d) KNEC Mathematical tables and electronic calculators may be used for calculations.
1-31 80
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
Copper oxide
Liquid droplets
Flame
Dry hydrogen
gas
Point(s)
Clamp
(a) State the observations made at the end of the experiment on:
(i) The cobalt II chloride papers. (1 mark)
(ii) Copper II oxide powder. (1 mark)
(b) (i) Why was excess hydrogen ignited? (1 mark)
(ii) Write a fully balanced equation for the reaction occurring at the flame at point(s).(1 mark)
2. A student used the reaction between steam and heated magnesium metal to collect a dry sample
of hydrogen gas. Complete the diagram to collect the gas. (3 marks)
Write the equation for the reaction producing the hydrogen gas in the above reaction. (1 mk)
P
Boiling tube
Beaker Water
Heat
(a) Identify the apparatus P and Q and state their uses. (2 marks)
4. (a) Define the term “Gay Lussac’s law”. (1 mark)
(b) When 100cm3 of gaseous hydrocarbon (Cx Hy) burn in 400cm3 of oxygen,
100cm3 of oxygen is unused, 200cm3 of steam are formed. Deduce the equation for the reaction and
the formula of the hydrocarbon. (2 marks)
5. If it takes 30 seconds for 100cm3 of carbon (IV) oxide to diffuse across a porous plate. How long
will it take 150cm3 of nitrogen (IV) oxide to diffuse across the same plate under similar
conditions? (C = 12.0, N = 14.0, O = 16.0) (2 marks)
6. Define Charles’ law. (1 mark)
7. The table below shows the solubility of a salt at various temperatures.
Temperature oC Solubility (g/100g water)
0 36
40 30
80 25
100 22
120 20
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
M N
(i) Identify the agents. (1 mark)
M -
N -
(ii) Write an equation for the compound formed when agent N is used with water containing calcium
nitrate salt. (1 mark)
(iii) A water engineer analyzed water from a borehole and found out that it contained
magnesium chloride impurities. State any two methods used to make the water suitable for
washing using agent N. (1 mark)
9. Calculate the percentage abundance of two other isotopes of element A with three isotopes, (30,
32, 35). Given that the R.A.M is 30.5 and percentage abundance of 35 is 5%. (2 marks)
10. An element Z has ionic configuration of 𝑍 + − 2.8. The element is burned in excess oxygen and
the product is then added to water. Write two possible equation for the reactions which took
place. (2 marks)
11. Phosphorus (III) oxide has a lower melting point than calcium chloride. Explain. (2 marks)
12. Describe how you would prepare silver carbonate starting with silver. (3 marks)
13. Use the table below to determine the enthalpy change for the reaction between hydrogen and
chlorine. (3 marks)
Bond Bond Energy kJ/mole
H–H 435
H – Cl 431
Cl – Cl 244
24. Draw and name two branched isomers of the compound whose chemical
formula is 𝐶5 𝐻12 . (2 marks)
25. (a) Complete the following table based on organic compounds. (1 mark)
Compound Reagents needed for preparation
(i) Ethyne
(ii) Ethane
(b) Write chemical equations to represent the reaction in (a) above. (2 marks)
(i)
(ii)
(c)An organic substance (Q) reacted with ethanoic acid to form pleasant smelling compound
𝐶𝐻3 𝐶𝐻𝑂𝑂𝐶𝐻2 𝐶𝐻2 𝐶𝐻3 .
(i) What conditions will be required to form the product? (1 mark)
(ii) If another compound with a chemical formulas 𝐶3 𝐻6 has to be formed from compound Q,
what would be the conditions required in this process. (1 mark)
26. (a)Give the formula of the Monomer used during the formation of the following polymer.
(1 mark)
H H H H
C C C C
Cl H Cl H
(b) State any use of the polymer in (a) above. (1 mark)
(c) Other than using universal indicator explain how one can differentiate between the following
chemicals.
Propanol and propanoic acid. (1 mark)
27. The melting points of oxygen and sulphur are -2160C and 1130C respectively yet the two
elements belong to group VI in the periodic table. Explain. (2 marks)
29. When dry chlorine is passed over heated iron in a combustion tube, a brown solid forms on the
cooler parts of the combustion tube.
(i) Name the brown solid. (1 mark)
(ii) Why does the brown solid form on the cooler parts of the combustion? (1 mark)
(iii) What will be the pH of the solution formed when the brown solid is dissolved in water?
(1 mark)
(iv)Chlorine gas is poisonous yet it is used to treat water. Explain. (1 mark)
30. The diagrams below show the apparatus used to investigate one of the properties of carbon.
Copper II oxide /
Aluminium oxide
carbon mixture
/ carbon mixture
Heat Heat
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
State and explain the observations made in each boiling tube. (2 marks)
31. The diagrams below show the apparatus used to investigate the properties of carbon IV oxide
gas.
Deflagrating spoon
Burning Mg
Burning sulphur
(i) State and explain the observations made in each gas jar. (2 marks)
(ii) State one industrial use of carbon (IV) oxide. (1 mark)
CHEMISTRY
PAPER 2 (THEORY)
TIME: 2 HOURS
NAME…………………………………………………………………………………….
SCHOOL……………………………………………… SIGN……………………….
INSTRUCTIONS TO CANDIDATES
(a) Write your name, school and index number in the spaces provided above.
(b) Sign and write the date of examination in the space provided above.
(c) Answer ALL the questions in the spaces provided.
(d) Mathematical tables and silent electronic calculators may be used.
P C D E
F G B H
Z
(i) What is the most likely nature of the solution formed by the oxide of Z? (1mk)
(ii) Chose a letter representing the most electronegative element. (1mk)
(iii) Write a balanced equation for the reaction between B and oxygen. (1mk)
(iv) Compare the reactivity of C and D. Explain your answer (2mks)
(v) An element Q has mass number 40 and 22 protons. What is the position of Q on the grid? (1mk)
(b) Study the information given and use it to answer the questions that follow
Formula NaCl MgCl2 AlCl3 SiCl4 PCl3 SCl2
Boiling point (0C) 1470 1420 ___ 60 75 60
Melting point (0C) 800 710 Sublimes at -70 -90 -80
1800C
3. In an experiment, 1.0 grams of an alloy of copper and magnesium were reacted with excess 4M
hydrochloric acid, and the gas collected measured at different time intervals. The results were
recorded as shown below.
a) (i) Write an equation for the chemical reaction taking place. (1mk)
Time in minutes Total volume of gas in / cm3
0 0
1 220
2 410
3 540
4 620
5 640
6 640
7 640
ii) Plot a graph of the volume of the gas (verticals axis) against time ( horizontal axis) (3mks)
(b) Using the graph determine
i) The rate of reaction at 2 ½ minutes. (1mk)
ii) The volume of the gas at the end of 3 ½ minutes. (1mk)
c) The synthesis of ammonia from nitrogen and hydrogen is carried out in the Haber process using
the equation below.
N2(g) + 3H2 2NH3(g) H°=-92kJ mol-1
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
4. Study the scheme below and answer the questions that follow.
Bond C–H C – Br Br – Br H – Br
(b) Bond energy kJ/mol 413 280 193 365
Hydrogen peroxide decomposes according to the equation given below;
H2O2 (l)
H2O(l) + ½ O2 (g) ; ΔH = -98 kJ/mol
If 6.8g of hydrogen peroxide contained in 75 cm3 of solution with water were completely
decomposed, determine the rise in temperature due to the reaction. (2mks)
(Specific heat capacity of water = 4.2 Jg-1K-1, density of water = 1 g/cm3, O = 16, H = 1)
(c) On the space provided below sketch the cooling curve that would be obtained when a
boiling tube containing water at 80oC is immersed in a freezing mixture maintained at -10oC. (3mks)
(d) Butane C4H10 cannot be prepared directly from its elements but its standard heat of formation
(ΔHθf) can be obtained indirectly. The following heats of combustion are given.
ΔHθC carbon (s) = -393 kJ/mol
ΔHθC H2 (g) = -286 kJ/mol
ΔHθC C4H10 = -2877 kJ/mol
(i) Draw an energy cycle diagram linking the heat of formation of butane with its heat of
combustion and the heat of combustion of its constituent elements. (2mks)
(ii) Calculate heat of formation of butane ΔHθf (C4H10). (2mks)
(e)Given that the lattice enthalpy of potassium chloride is +690 kJ/mol and hydration enthalpies of
K+ and Cl- are -322 kJ and -364 kJ respectively. Calculate the enthalpy of solution of potassium
chloride. (2mks)
6. a) An aqueous solution of hydrogen peroxide decomposes according to the equation
2H2O2(l) 2H2O(l) + O2(g)
This reaction is fast at 200C in the presence of manganese (IV) oxide.
(i) What is the role of manganese (IV) oxide in the reaction. (1mk)
(ii) Sketch graphs on the same grid provided below showing how the volume of oxygen (vertical
axis) varies with
Time
(b) (i) Write the equation for the manufacture of ammonia hence explain how the increase in
pressure affects the position of the equilibrium. (2mks)
(ii) The reaction in b(i) above is exothermic, what is the effect of raising temperature on the
equilibrium position? (1mk)
6. a) Give the names of the following compounds.
(i) CH3CH2CH2CH2OH .……………………………………………………… (1mk)
(ii) CH3-COO-CH2-CH3……………………………………………………….. (1mk)
b).One of the two formulae in (a) above represents a sweet smelling compound. Give the names of
the two organic compounds that can be used to prepare this compound in the laboratory. (2mks)
c), Ethane and Ethene react with Bromine according to the following equations given below:
i. C2 H6 g Br2 g C2 H5 Brl HBr g
CH CH2 CH CH2
C5H5 C6H5 n
What is meant by polymerization? (1mk)
KCSE Replica Marking Schemes - 0746 222 000 / 0742 999 000
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